{"id":"W2088199433","doi":"10.1002/poc.655","title":"Thermolysis of <i>N</i>‐tetramethylpiperidinyl triphenylacetate: homolytic fragmentation of a TEMPO ester","year":2003,"lang":"en","type":"article","venue":"Journal of Physical Organic Chemistry","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Homolysis; Thermal decomposition; Bond cleavage; Adduct; Triphenylmethane; Benzene; Reaction rate constant; Medicinal chemistry; Decomposition; Radical; Photochemistry; Polymer chemistry; Organic chemistry; Kinetics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001880749,0.0002571132,0.0007515435,0.00002529928,0.00004193237,0.00001184889,0.0003117358,0.0001224046,0.001411788],"category_scores_gemma":[0.0002238438,0.0002214831,0.0004810609,0.0002960646,0.0001734866,0.0001145615,0.00002248644,0.0004418212,0.000001622586],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009663239,"about_ca_system_score_gemma":0.0002036807,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002241568,"about_ca_topic_score_gemma":1.904817e-7,"domain_scores_codex":[0.9982391,0.00002620282,0.0007909959,0.0001988097,0.0004885977,0.0002563011],"domain_scores_gemma":[0.9984532,0.0002198286,0.0006464589,0.0002996437,0.0002602772,0.0001205909],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001351392,0.0007107391,0.0002303296,0.0007766209,0.0004503344,0.00001076349,0.0006936667,0.00001370604,0.9964643,0.00001723595,0.00005148018,0.0004456433],"study_design_scores_gemma":[0.001502345,0.00009178945,0.000031115,0.0001513016,0.0003297991,0.00007604658,0.0007212834,0.0000153585,0.9961972,0.0005008599,0.0001934621,0.0001894162],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.992403,0.0005763604,0.0001635776,0.00004382459,0.00002790221,0.0000367304,0.00001594636,0.00001031138,0.006722395],"genre_scores_gemma":[0.9992412,0.00009428414,0.0001171885,0.00001158772,0.0001399185,0.000003749915,0.00000367757,0.00002894972,0.000359464],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006838228,"threshold_uncertainty_score":0.999501,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006399268036345532,"score_gpt":0.2278936977956099,"score_spread":0.2214944297592643,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}