{"id":"W2088539547","doi":"10.1139/v08-140","title":"Chemoenzymatic synthesis of ring <sup>18</sup>O-labeled sialic acid","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Simon Fraser University","keywords":"Chemistry; Sialic acid; Ring (chemistry); Yield (engineering); Stereochemistry; Trifluoromethanesulfonate; Neuraminic acid; N-Acetylneuraminic acid; Catalysis; Organic chemistry; Biochemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001822387,0.0003878904,0.000232341,0.0002044439,0.000172002,0.0001766796,0.0003097122,0.0002259562,0.001282016],"category_scores_gemma":[0.0001646889,0.000158735,0.0001694308,0.0002953328,0.0001910172,0.0002120189,0.0003233517,0.0005247651,0.0007741554],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003154258,"about_ca_system_score_gemma":0.000432215,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009057558,"about_ca_topic_score_gemma":0.001806916,"domain_scores_codex":[0.9998796,0.00001620523,0.000009821549,0.00002859773,0.00002734488,0.00003855276],"domain_scores_gemma":[0.9999125,0.00001297727,0.00002276649,0.00001680072,0.00001805089,0.0000169798],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005257389,0.00002089142,0.00007517064,0.00003937182,0.000004248286,0.00005947922,0.00002120475,0.0001293961,0.9951108,0.0004610204,0.00007169741,0.003954155],"study_design_scores_gemma":[0.000008580895,0.0000827785,0.0002887849,0.000001918202,0.000005962468,0.00008123139,0.000004854197,0.0001567194,0.9960932,0.00003994684,0.003233171,0.000002926728],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9187278,0.002329802,0.05796975,0.0002707753,0.0001479998,0.0003521477,0.001360452,0.0003870926,0.01845423],"genre_scores_gemma":[0.9509104,0.002589579,0.03633811,0.00009114949,0.00002666887,0.0001566064,0.0009881562,0.00007496709,0.008824454],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001282016,"threshold_uncertainty_score":0.004288733,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01715862096744974,"score_gpt":0.1981112424671053,"score_spread":0.1809526214996555,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}