{"id":"W2088565716","doi":"10.1021/ja025773x","title":"Coordination-Driven Self-Assembly:  Solids with Bidirectional Porosity","year":2002,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":130,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Division of Chemistry; National Institute of General Medical Sciences; National Institutes of Health; National Science Foundation","keywords":"Supramolecular chemistry; Chemistry; Porosity; Self-assembly; Solid-state; Nanotechnology; Covalent bond; Polymer; Molecule; Nanoscopic scale; Lattice (music); Ligand (biochemistry); Porous medium; Crystal structure; Crystal engineering; Crystallography; Organic chemistry; Materials science; Receptor; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001307454,0.0001476037,0.0003098427,0.00001024223,0.0001785735,0.00003920722,0.0004636123,0.000078645,0.0005167672],"category_scores_gemma":[0.00007507734,0.00009268778,0.0004297591,0.0003769143,0.0002316414,0.00007898833,0.00007201532,0.0005519396,0.00001049592],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002186863,"about_ca_system_score_gemma":0.00004835958,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001326717,"about_ca_topic_score_gemma":5.516471e-7,"domain_scores_codex":[0.9988288,0.00002176824,0.000327673,0.000160345,0.0004590157,0.0002023662],"domain_scores_gemma":[0.9984591,0.0002006381,0.0007627474,0.0002832571,0.0001743232,0.0001199424],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000116934,0.0003764945,0.005753699,0.00001462658,0.0002980923,9.339294e-7,0.0002138087,0.00002327796,0.9563466,0.00007270581,0.03526941,0.001618677],"study_design_scores_gemma":[0.0005942707,0.00004459982,0.002190854,0.00009841756,0.0003040923,0.0002547857,0.0005266007,0.003647463,0.9662104,0.0002366646,0.02555222,0.0003396574],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.99229,0.00008117475,0.000424277,0.005725444,0.0000416559,0.00003324002,0.000007227551,0.00003635602,0.001360583],"genre_scores_gemma":[0.9888404,0.0001114329,0.00963318,0.0005343516,0.0004387365,0.000005815939,8.781203e-7,0.00002204013,0.0004131764],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009863789,"threshold_uncertainty_score":0.5658238,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009876798452386119,"score_gpt":0.227465322096959,"score_spread":0.2175885236445729,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}