{"id":"W2088727932","doi":"10.1021/om7006198","title":"Stabilization of a Transient Diorganogermylene by an N-Heterocyclic Carbene","year":2007,"lang":"en","type":"article","venue":"Organometallics","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":79,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Carbene; Chemistry; Adduct; Transient (computer programming); Photochemistry; Medicinal chemistry; Polymer chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002721174,0.0004243364,0.0005483645,0.0000920239,0.0001073645,0.00003692998,0.0006162185,0.0003819439,0.006021398],"category_scores_gemma":[0.00008738594,0.0004469606,0.0001870894,0.0005113464,0.0002128756,0.0002531302,0.0001112388,0.0002915258,0.00001941702],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002514809,"about_ca_system_score_gemma":0.00005841585,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004025158,"about_ca_topic_score_gemma":0.00003017084,"domain_scores_codex":[0.9971532,0.00001844045,0.0009535701,0.0006669826,0.0005918416,0.0006159178],"domain_scores_gemma":[0.998035,0.00009330238,0.0003317391,0.001036633,0.0001471835,0.0003562068],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005216663,0.0004460331,0.001423791,0.0001887158,0.00008242657,0.000006117227,0.000587862,0.000004274573,0.9933667,0.00008129574,0.0001123623,0.003648286],"study_design_scores_gemma":[0.0008366721,0.00006068181,0.0003679838,0.00002814932,0.0001034331,0.00004146931,0.0005337751,0.00003461564,0.9875119,0.00006653075,0.009952615,0.0004622287],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.985532,0.0005517009,0.003986363,0.00003920891,0.0001698285,0.00009744098,0.0001385869,0.0001928347,0.00929203],"genre_scores_gemma":[0.997653,0.0002160933,0.0003867169,0.0000751617,0.0002275272,0.000005215667,0.0003799886,0.0001318353,0.0009244317],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01212102,"threshold_uncertainty_score":0.9997982,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008175414668929076,"score_gpt":0.2355514378272646,"score_spread":0.2273760231583355,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}