{"id":"W2088847905","doi":"10.1021/jo030353r","title":"Carbonylative Ring Expansion of Aziridines to β-Lactams with Rhodium-Complexed Dendrimers on a Resin","year":2004,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":59,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Rhodium; Dendrimer; Ring (chemistry); Polymer chemistry; Chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002071895,0.0001399244,0.0002389359,0.00002054153,0.00004645714,0.000008048633,0.0002745887,0.00006931068,0.00006573043],"category_scores_gemma":[0.0001517208,0.00008525039,0.0001126891,0.0001650758,0.00007089409,0.000003127567,0.00006003418,0.0001365356,0.000001560725],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004630549,"about_ca_system_score_gemma":0.0001107164,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001478295,"about_ca_topic_score_gemma":0.000006839149,"domain_scores_codex":[0.9991756,0.00002300194,0.000291239,0.0001293652,0.0002363723,0.0001443876],"domain_scores_gemma":[0.9991854,0.00003389038,0.000285488,0.0002579392,0.0001392195,0.0000981089],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004344785,0.00005279837,0.0001009734,0.00001604847,0.0001262754,0.000003869894,0.0001297814,0.0003866314,0.9985009,0.000001206711,0.00006558436,0.0001814532],"study_design_scores_gemma":[0.0005704444,0.0002007628,0.0002797667,0.0001295675,0.0001084185,0.00007017561,0.0003518758,0.000002515509,0.9979644,0.00002852606,0.000183404,0.0001101894],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981722,0.0001903755,0.0005369783,0.0005155652,0.00001465029,0.00003832365,0.000002976753,0.000002510227,0.0005264574],"genre_scores_gemma":[0.9990516,0.0000663865,0.0005148845,0.0000726181,0.0001725245,5.756327e-7,0.000002809107,0.0000182544,0.0001003928],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008793918,"threshold_uncertainty_score":0.347641,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007600069458200322,"score_gpt":0.2244660815634088,"score_spread":0.2168660121052085,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}