{"id":"W2088856679","doi":"10.1021/jo100931a","title":"Electron Transfer Properties of Alkoxyl Radicals. A Time-Resolved Kinetic Study of the Reactions of the<i>tert</i>-Butoxyl, Cumyloxyl, and Benzyloxyl Radicals with Alkyl Ferrocenes","year":2010,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Institute for Nanotechnology","funders":"Ministero dell’Istruzione, dell’Università e della Ricerca","keywords":"Chemistry; Radical; Reactivity (psychology); Electron transfer; Alkoxy group; Delocalized electron; Reaction rate constant; Photochemistry; Alkyl; Kinetics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005159159,0.0002793501,0.0006147173,0.00002467884,0.0001626821,0.00001926541,0.001007153,0.0001798464,0.0006549249],"category_scores_gemma":[0.0002027665,0.0001288918,0.0001920572,0.0002547263,0.0008695927,0.00007514618,0.0001029132,0.0009873919,4.677626e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000027592,"about_ca_system_score_gemma":0.0002787012,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006407521,"about_ca_topic_score_gemma":0.00004301714,"domain_scores_codex":[0.9977134,0.00008259336,0.0009811849,0.0001873016,0.000750859,0.0002846774],"domain_scores_gemma":[0.9980848,0.0001553075,0.0006893374,0.0007267601,0.0002203388,0.0001234128],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002964287,0.000793464,0.001681049,0.0003663896,0.0002769245,0.000002429671,0.0007973916,0.000009652199,0.9955106,0.000003249675,0.0001052299,0.0001572332],"study_design_scores_gemma":[0.001817701,0.0001543331,0.002490751,0.000567615,0.0005204169,0.0005613973,0.0005974384,0.00004184473,0.9927247,0.00003317352,0.0003396649,0.0001510233],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9975829,0.001284154,0.00001175764,0.0006328596,0.00004535799,0.0001571923,0.0000122402,0.00001004151,0.0002635383],"genre_scores_gemma":[0.9990502,0.0002047391,0.00002267536,0.0000250079,0.0001401674,0.000002804317,4.834648e-7,0.00004231595,0.0005116269],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002785917,"threshold_uncertainty_score":0.7170968,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006065102638784132,"score_gpt":0.1884552519987401,"score_spread":0.182390149359956,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}