{"id":"W2088990218","doi":"10.1021/ma0706733","title":"Synthesis and Characterization of Hyperbranched Polyethylenes Tethered with Polyhedral Oligomeric Silsesquioxane (POSS) Nanoparticles by Chain Walking Ethylene Copolymerization with Acryloisobutyl-POSS","year":2007,"lang":"en","type":"article","venue":"Macromolecules","topic":"Silicone and Siloxane Chemistry","field":"Materials Science","cited_by":97,"is_retracted":false,"has_abstract":true,"ca_institutions":"Laurentian University","funders":"","keywords":"Macromonomer; Silsesquioxane; Materials science; Polymer chemistry; Copolymer; Differential scanning calorimetry; Gel permeation chromatography; Thermogravimetric analysis; Polymer; Nanoparticle; Chemical engineering; Composite material; Nanotechnology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001169621,0.0002855972,0.0001213283,0.0001336655,0.00005704902,0.000188583,0.00009053825,0.0002254252,0.000386131],"category_scores_gemma":[0.0001322234,0.0001350945,0.0001434626,0.00009141568,0.0001342815,0.0002442456,0.0001127027,0.0002207892,0.0001645368],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000982091,"about_ca_system_score_gemma":0.00007021389,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001693369,"about_ca_topic_score_gemma":0.0003635949,"domain_scores_codex":[0.9999336,0.000006659719,0.000006437583,0.00001701458,0.00002653353,0.000009690969],"domain_scores_gemma":[0.9998678,0.0000208802,0.00005916442,0.000009702399,0.00002086843,0.00002165312],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000005323024,0.000003377923,0.00003656792,0.000007465089,8.338076e-7,0.000009527928,0.000004075956,0.0000278764,0.9997119,0.000007068269,0.000001249767,0.0001845596],"study_design_scores_gemma":[0.000002251509,0.0001269497,0.001477691,0.000001935567,0.00000517955,0.00005003055,0.000006436717,0.0004386719,0.9975914,0.000005847422,0.0002916636,0.00000202184],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9954919,0.000296347,0.003726493,0.00001618234,0.00000657711,0.00002472909,0.00007233211,0.00002448298,0.0003411018],"genre_scores_gemma":[0.9913834,0.0005077932,0.006370287,0.00002162473,0.000005783699,0.00003960176,0.0001450256,0.00002007877,0.001506402],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000386131,"threshold_uncertainty_score":0.001291692,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005029591764952641,"score_gpt":0.2034266265065564,"score_spread":0.1983970347416038,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}