{"id":"W2089463504","doi":"10.1021/ja001244m","title":"Control of Chirality of an Azobenzene Liquid Crystalline Polymer with Circularly Polarized Light","year":2000,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Liquid Crystal Research Advancements","field":"Materials Science","cited_by":222,"is_retracted":false,"has_abstract":true,"ca_institutions":"Royal Military College of Canada; Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Azobenzene; Chirality (physics); Circular polarization; Chemistry; Enantiomer; Polymer; Liquid crystal; Liquid crystalline; Polarized light microscopy; Irradiation; Homochirality; Photochemistry; Optics; Crystallography; Stereochemistry; Organic chemistry; Physics; Chiral symmetry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001020937,0.0002653474,0.0001374804,0.000204927,0.0002089203,0.000493793,0.0001952632,0.0001769504,0.0009495101],"category_scores_gemma":[0.0002231173,0.0001266787,0.00008925498,0.0001936963,0.0003715088,0.0001931179,0.0001313176,0.0003523477,0.0001839394],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002756812,"about_ca_system_score_gemma":0.0002197243,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005596704,"about_ca_topic_score_gemma":0.000716085,"domain_scores_codex":[0.9998872,0.00001244974,0.000004427096,0.00002632406,0.00003654424,0.00003295928],"domain_scores_gemma":[0.999804,0.00006311043,0.0000487311,0.00001425532,0.00002388693,0.00004616791],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006153799,0.00001717498,0.00009745156,0.00001527895,0.000001922388,0.0000405222,0.00001756479,0.00006968242,0.998072,0.0003282939,0.00003614377,0.001242491],"study_design_scores_gemma":[0.00001363611,0.00004603176,0.0004374546,0.000001376329,0.000002802634,0.00003659322,0.000007092669,0.0007975416,0.9981035,0.00003717981,0.0005132147,0.00000335299],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9931874,0.0003967596,0.002253957,0.0001027025,0.0000396636,0.00001772287,0.00006234417,0.00006422806,0.003875188],"genre_scores_gemma":[0.9969433,0.0003690245,0.001227762,0.00003002389,0.00001725456,0.000009325543,0.00005854877,0.00001716357,0.001327675],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009495101,"threshold_uncertainty_score":0.003176391,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008121626684753464,"score_gpt":0.2632932042918605,"score_spread":0.255171577607107,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}