{"id":"W2089530708","doi":"10.1039/b908515g","title":"Interrupting the Nazarov reaction: domino and cascade processes utilizing cyclopentenyl cations","year":2009,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":257,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Nucleophile; Cascade reaction; Domino; Cyclopentenone; Cascade; Cycloaddition; Conjugated system; Combinatorial chemistry; Photochemistry; Silylation; Computational chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002256714,0.0004550651,0.0002371326,0.0002834747,0.0002802131,0.000513242,0.0004648106,0.0003624539,0.001296175],"category_scores_gemma":[0.0002172698,0.0002024958,0.0002328444,0.0002029256,0.0005026095,0.00111125,0.0007392777,0.0006968005,0.0003643248],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004844531,"about_ca_system_score_gemma":0.0003452897,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003798201,"about_ca_topic_score_gemma":0.0008152091,"domain_scores_codex":[0.9998457,0.00001667692,0.00001025868,0.00004255098,0.00003477344,0.00004994107],"domain_scores_gemma":[0.9999201,0.00001904403,0.00002608467,0.00001406677,0.000006761059,0.00001382165],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004461499,0.0001223108,0.0004277549,0.0003827258,0.00002743974,0.0006062745,0.0003509001,0.002604367,0.9015645,0.04680182,0.0006954906,0.04597036],"study_design_scores_gemma":[0.00005941619,0.0004735664,0.0003946628,0.00001756935,0.00001968311,0.000471665,0.00004895297,0.003903603,0.9636579,0.003284349,0.02762575,0.00004292446],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8403612,0.009882619,0.09535876,0.0004434325,0.0003786082,0.0003985972,0.0003066239,0.0004782036,0.0523919],"genre_scores_gemma":[0.9680437,0.00361358,0.01984742,0.00008515493,0.00005165519,0.0001124012,0.00008446455,0.00002973876,0.008131921],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001296175,"threshold_uncertainty_score":0.004336119,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04119833378253603,"score_gpt":0.2946942687890431,"score_spread":0.2534959350065071,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}