{"id":"W2089552100","doi":"10.1071/ch02165","title":"Synthesis with Glycosynthases: Cello-Oligomers of Isofagomine and a Tetrahydrooxazine as Cellulase Inhibitors","year":2003,"lang":"en","type":"article","venue":"Australian Journal of Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Australian Research Council; Networks of Centres of Excellence of Canada","keywords":"Chemistry; Biocatalysis; Cellulase; Glycoside hydrolase; Stereochemistry; Enzyme; Macromolecule; Oligosaccharide; Resorcinarene; Substrate (aquarium); Biochemistry; Organic chemistry; Reaction mechanism; Catalysis; Molecule","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001389894,0.0005250008,0.0002891598,0.0001387291,0.0001088038,0.0002592949,0.000241207,0.0003064373,0.0009163172],"category_scores_gemma":[0.0001297294,0.0001725972,0.0002001645,0.0001951022,0.0001461091,0.000229047,0.0001557287,0.0005047423,0.0004511425],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003326756,"about_ca_system_score_gemma":0.0003205622,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008717565,"about_ca_topic_score_gemma":0.001220293,"domain_scores_codex":[0.9999102,0.000012,0.000007552263,0.00001940513,0.00002141369,0.00002936253],"domain_scores_gemma":[0.9998801,0.00001516159,0.00003767033,0.00001331647,0.00001519062,0.00003868769],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004666859,0.00001522484,0.0000378426,0.0000197822,0.000003785691,0.00002193308,0.00001379602,0.0000898147,0.9989207,0.0001079961,0.00001035259,0.0007120802],"study_design_scores_gemma":[0.00001050345,0.0001527605,0.000429833,0.000003045243,0.000008485566,0.00004436678,0.000006462913,0.0002262614,0.9978901,0.00001729938,0.00120838,0.00000255704],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9901225,0.0009778085,0.006232867,0.00004235668,0.00002494698,0.00008107504,0.0003075412,0.00007200188,0.002138914],"genre_scores_gemma":[0.9883582,0.0009105541,0.006483953,0.00004107778,0.000007441868,0.00007624354,0.0007006052,0.00003065121,0.003391356],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009163172,"threshold_uncertainty_score":0.003065407,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008460068216147056,"score_gpt":0.2076664162193903,"score_spread":0.1992063480032432,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}