{"id":"W2089766741","doi":"10.1016/s0009-2614(02)01545-2","title":"Pressure-dependent Raman spectroscopy of metal-oxo multiple bonds in rhenium(V) and osmium(VI) complexes","year":2002,"lang":"en","type":"article","venue":"Chemical Physics Letters","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":14,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université de Montréal; McGill University","funders":"","keywords":"Osmium; Rhenium; Raman spectroscopy; Metal; Chemistry; Spectroscopy; Photochemistry; Crystallography; Inorganic chemistry; Ruthenium; Organic chemistry; Physics; Optics; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001675885,0.0002378059,0.0002067289,0.0002580832,0.0003509379,0.0003513014,0.0006624089,0.0004035012,0.001645811],"category_scores_gemma":[0.0003934567,0.0002603276,0.0001137223,0.0001545829,0.0005667055,0.0003361596,0.0003598092,0.0005908224,0.0001712122],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001697578,"about_ca_system_score_gemma":0.00009094521,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005283434,"about_ca_topic_score_gemma":0.0006529154,"domain_scores_codex":[0.9998306,0.00002643825,0.00000524109,0.00003509514,0.00006960816,0.00003301864],"domain_scores_gemma":[0.9998028,0.00008546318,0.00005002902,0.00001755544,0.00002324135,0.0000209838],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002176529,0.00002418062,0.0004798918,0.00007575495,0.00001450179,0.0001220517,0.0002004895,0.0002143309,0.9959731,0.0006357949,0.0001450353,0.001897287],"study_design_scores_gemma":[0.00002348002,0.000173766,0.00548339,0.000009252755,0.00001163432,0.0002073403,0.0001702496,0.003400456,0.9891856,0.0002466069,0.001074808,0.00001351308],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966688,0.0003613874,0.0009330336,0.00008702063,0.00001182241,0.000005892776,0.00004319892,0.00003934901,0.001849476],"genre_scores_gemma":[0.9986153,0.0001232327,0.0004135362,0.00002246422,0.000006421608,0.000006102336,0.00004942814,0.00001099476,0.0007524716],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001645811,"threshold_uncertainty_score":0.005505741,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01988862025543851,"score_gpt":0.2361334186662746,"score_spread":0.2162447984108361,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}