{"id":"W2089923076","doi":"10.1021/ja048911m","title":"Me<sub>2</sub>AlCH<sub>2</sub>PMe<sub>2</sub>: A New, Bifunctional Cocatalyst for the Ni(II)-Catalyzed Oligomerization of PhSiH<sub>3</sub>","year":2004,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":114,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Bifunctional; Moiety; Nucleophile; Catalysis; Quinuclidine; Methylaluminoxane; Reagent; Monomer; Medicinal chemistry; Lewis acids and bases; Stereochemistry; Organic chemistry; Polymerization; Metallocene","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005447118,0.0002476682,0.000104133,0.00009808079,0.00007363346,0.0001922024,0.0001551035,0.0001966349,0.0009301708],"category_scores_gemma":[0.0000668003,0.00008439604,0.00009794013,0.00009337466,0.0001469411,0.0002136004,0.0001609807,0.0002308008,0.0003850611],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001767628,"about_ca_system_score_gemma":0.00009656559,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004552588,"about_ca_topic_score_gemma":0.00105207,"domain_scores_codex":[0.999956,0.00000457736,0.000003055409,0.00001043982,0.00001546627,0.00001034499],"domain_scores_gemma":[0.9999712,0.000004718852,0.00000911672,0.000004114738,0.000004963084,0.000005962026],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002756687,0.000005794162,0.00009393303,0.00004160957,0.000003085369,0.00003640924,0.000008793608,0.00004274036,0.9978945,0.00009131092,0.00003061828,0.001723678],"study_design_scores_gemma":[0.000002027759,0.00003614456,0.0006018811,9.334788e-7,0.000003827967,0.0001223182,0.000005410571,0.0002941618,0.9974079,0.00001117212,0.001512663,0.000001551327],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9835432,0.00169657,0.009859524,0.00009752972,0.00003105043,0.00003433035,0.0002974873,0.0002169794,0.004223392],"genre_scores_gemma":[0.9922106,0.0004345546,0.004712011,0.00002647301,0.00000606258,0.00001403351,0.0001775194,0.00003059955,0.002388261],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009301708,"threshold_uncertainty_score":0.00311172,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00821582433503447,"score_gpt":0.2214068292381869,"score_spread":0.2131910049031524,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}