{"id":"W2090069273","doi":"10.1039/b101380g","title":"Kinetics of the gas-phase reaction of atomic chlorine with selected monoterpenes","year":2001,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Reaction rate constant; Myrcene; Chlorine atom; Halogen; Physical chemistry; Reaction mechanism; Reaction rate; Computational chemistry; Analytical Chemistry (journal); Kinetics; Organic chemistry; Catalysis; Medicinal chemistry; Limonene; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002740337,0.0004308001,0.0002152037,0.0003193339,0.0001825999,0.000351807,0.0005029512,0.0003695331,0.002074002],"category_scores_gemma":[0.0004844945,0.0001707619,0.0002979246,0.0001753196,0.0002788199,0.0003241904,0.0001811967,0.0003711317,0.0004660957],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000868628,"about_ca_system_score_gemma":0.0002560233,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.006850211,"about_ca_topic_score_gemma":0.004567483,"domain_scores_codex":[0.9998299,0.00001793499,0.000005208817,0.00004831348,0.00005282079,0.00004579872],"domain_scores_gemma":[0.9996901,0.000149807,0.00005326018,0.00002106709,0.00006170681,0.00002408678],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003556784,0.0000228656,0.004347103,0.00007635901,0.00002595343,0.00009380548,0.00008161115,0.001010411,0.9921565,0.000123028,0.00008362238,0.00162321],"study_design_scores_gemma":[0.00003389103,0.0002733885,0.01582401,0.000005306947,0.00001659919,0.00008403595,0.00006876269,0.008690757,0.9739144,0.00007288724,0.0009961741,0.00001978694],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9970984,0.0004046618,0.001015728,0.00003645208,0.000004906593,0.00001618204,0.0005021886,0.00005714365,0.0008643782],"genre_scores_gemma":[0.9979658,0.0001852547,0.0003884396,0.00001028879,0.000002585772,0.00001017291,0.0004794876,0.00001601853,0.0009419053],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006850211,"threshold_uncertainty_score":0.01362067,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009357445456619286,"score_gpt":0.2137833897271682,"score_spread":0.2044259442705489,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}