{"id":"W2090196510","doi":"10.1007/s00775-006-0187-5","title":"Probing structural changes in the α and β domains of copper- and silver-substituted metallothionein by emission spectroscopy and electrospray ionization mass spectrometry","year":2006,"lang":"en","type":"article","venue":"JBIC Journal of Biological Inorganic Chemistry","topic":"Trace Elements in Health","field":"Nursing","cited_by":27,"is_retracted":false,"has_abstract":false,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Electrospray ionization; Copper; Excited state; Analytical Chemistry (journal); Crystallography; Mass spectrometry; Ion; Emission spectrum; Spectral line; Organic chemistry; Chromatography","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005325121,0.0001699542,0.0003309289,0.0000511356,0.0001084081,0.00004209573,0.0001428658,0.0001776233,0.00003265289],"category_scores_gemma":[0.0001595481,0.0001066531,0.00002643869,0.0002739078,0.0001889572,0.0000886686,0.00003396585,0.000455495,6.872216e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001259439,"about_ca_system_score_gemma":0.00002591548,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001796039,"about_ca_topic_score_gemma":0.000008338809,"domain_scores_codex":[0.998728,0.0001063752,0.0004760624,0.0002116929,0.0002128092,0.0002650779],"domain_scores_gemma":[0.9991764,0.0001722298,0.0004357017,0.00009970265,0.0000495096,0.00006645395],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001177718,0.00004596548,0.04407483,0.0000734386,0.0000124172,0.000005505736,0.0001265377,8.800704e-7,0.9552475,0.00003394943,0.00009047904,0.0001707475],"study_design_scores_gemma":[0.0009701562,0.0003651236,0.05105231,0.00008296817,0.00003516826,0.0003266588,0.0003376528,0.00003260481,0.9453505,0.001265156,0.00005463387,0.000127084],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9945275,0.00362112,0.0001032234,0.001475136,0.00006444012,0.0001537697,0.000008565139,0.00001043025,0.00003582465],"genre_scores_gemma":[0.9975998,0.000450312,0.001700743,0.00007320406,0.0001456186,0.000001262772,0.00001298321,0.000009542012,0.000006474284],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009896995,"threshold_uncertainty_score":0.4349186,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009998728573861144,"score_gpt":0.2624821321465522,"score_spread":0.2524834035726911,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}