{"id":"W2090371844","doi":"10.1155/2000/162973","title":"2D <sup>1</sup>H and <sup>13</sup>C NMR studies of the adducts obtained by cyclostereoselective oligomerization of <i>α</i>,<i>β</i>‒unsaturated arylidenketones promoted by 6 amino‒1,3‒dimethyl uracil","year":2000,"lang":"en","type":"article","venue":"Journal of Spectroscopy","topic":"Click Chemistry and Applications","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Moncton Hospital; Université de Moncton","funders":"European Regional Development Fund; Consejo Nacional de Ciencia y Tecnología","keywords":"Chemistry; Adduct; Nucleophile; Uracil; Monomer; Reagent; Derivative (finance); Condensation; Stereochemistry; Medicinal chemistry; Organic chemistry; DNA","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001384881,0.000359993,0.0001428178,0.0001344325,0.0001794963,0.0001591286,0.0002374267,0.0002156324,0.003446042],"category_scores_gemma":[0.0001595397,0.0001660046,0.00007062007,0.0002102392,0.0002087813,0.0002508714,0.0000971229,0.0003828594,0.0006106616],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001496167,"about_ca_system_score_gemma":0.0001668014,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007504005,"about_ca_topic_score_gemma":0.001702458,"domain_scores_codex":[0.9999474,0.000006542906,0.000002171315,0.00001331104,0.00001580199,0.00001476997],"domain_scores_gemma":[0.9999256,0.00001228156,0.00002891304,0.000006165307,0.00001278949,0.000014208],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001247013,0.00001144457,0.0001593937,0.00003297445,0.000004600657,0.00007553616,0.00005260049,0.0001421155,0.9979261,0.0001562606,0.000117456,0.001196803],"study_design_scores_gemma":[0.000006529357,0.0001218851,0.002511509,0.000003471295,0.00001124734,0.0002167524,0.00004088335,0.0004483393,0.9937855,0.00005094541,0.002790639,0.0000122959],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9844486,0.0008161939,0.007293166,0.00008891104,0.00005315134,0.0000169122,0.0009738551,0.0001317697,0.006177623],"genre_scores_gemma":[0.9899449,0.0008835886,0.003906011,0.00006510437,0.0000148085,0.00002062632,0.001269917,0.00004851906,0.003846538],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003446042,"threshold_uncertainty_score":0.01152813,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00990234958240476,"score_gpt":0.2602166504820555,"score_spread":0.2503143008996507,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}