{"id":"W2090373531","doi":"10.1016/s1010-6030(00)00386-5","title":"Kinetics of the photoinduced dissociative electron transfer reduction of the antimalarial endoperoxide, Artemisinin","year":2001,"lang":"en","type":"article","venue":"Journal of Photochemistry and Photobiology A Chemistry","topic":"Malaria Research and Control","field":"Medicine","cited_by":27,"is_retracted":false,"has_abstract":false,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Reaction rate constant; Excited state; Electron transfer; Bond-dissociation energy; Singlet state; Physical chemistry; Photochemistry; Marcus theory; Dissociation (chemistry); Computational chemistry; Kinetics; Atomic physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000332604,0.0001768192,0.0005140516,0.00001788041,0.00006304609,0.000006023225,0.0002828689,0.0003025316,0.000226906],"category_scores_gemma":[0.0004490959,0.0001023054,0.0003405939,0.0002044041,0.0004508759,0.00003353972,0.00004568613,0.0008043445,1.198347e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006017975,"about_ca_system_score_gemma":0.0002647415,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001194354,"about_ca_topic_score_gemma":8.153039e-7,"domain_scores_codex":[0.9985538,0.00009437338,0.0006364317,0.0001699501,0.0002881098,0.000257326],"domain_scores_gemma":[0.9986767,0.0001114872,0.0004545945,0.0002985223,0.0003456785,0.0001130716],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002315026,0.0002708847,0.002511024,0.0001596521,0.0002721308,0.000008987901,0.0001573965,0.000002188358,0.9940922,0.000005935995,0.0001326984,0.00007188791],"study_design_scores_gemma":[0.00306521,0.0002557329,0.004896691,0.0002235093,0.0002131684,0.001753238,0.0002151402,0.00000884888,0.9888824,0.00009475531,0.0003077883,0.00008348654],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966667,0.0003873918,0.00001037385,0.0009330682,0.00009126846,0.0003272859,0.00003112259,0.000003178852,0.00154967],"genre_scores_gemma":[0.9988947,0.0002287891,0.00002313623,0.00004481892,0.0002504583,0.00001145777,0.000004746033,0.00001033805,0.000531574],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005209756,"threshold_uncertainty_score":0.4171892,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008508062799556652,"score_gpt":0.252997164387589,"score_spread":0.2444891015880324,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}