{"id":"W2091001585","doi":"10.1107/s1600536803005622","title":"1,3-Bis(2,2′:6′,2′′-terpyridin-4′-yl)benzene, a new dinucleating bis(tridentate) ligand, as its dichloromethane solvate","year":2003,"lang":"en","type":"article","venue":"Acta Crystallographica Section E Structure Reports Online","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Pyridine; Dihedral angle; Chemistry; Dichloromethane; Benzene; Ligand (biochemistry); Crystal structure; Solvent; Crystallography; Stereochemistry; Medicinal chemistry; Hydrogen bond; Molecule; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006283036,0.00075603,0.00116794,0.0008723243,0.0004355986,0.0001869798,0.0001979984,0.0004639276,0.001619091],"category_scores_gemma":[0.001548161,0.0005997096,0.0005826697,0.001558061,0.0001497811,0.0004564536,0.0001060146,0.0009259019,5.13806e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001020826,"about_ca_system_score_gemma":0.000485515,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003550512,"about_ca_topic_score_gemma":0.0003459182,"domain_scores_codex":[0.9952059,0.0002201786,0.001522673,0.001178475,0.001047025,0.0008257571],"domain_scores_gemma":[0.9967734,0.0001397888,0.0009423432,0.001014121,0.0004367683,0.0006936322],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0003375195,0.0001843708,0.006409875,0.0001887916,0.0004766204,0.0004795755,0.0001709489,0.00002395389,0.9895205,0.0000442578,0.0009014359,0.001262127],"study_design_scores_gemma":[0.002394825,0.001568257,0.02548865,0.0005559308,0.001051317,0.02125422,0.0006447155,0.00008140365,0.0490765,0.002314198,0.8941697,0.001400315],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9907815,0.001637395,0.0001349125,0.001060657,0.001569787,0.0009153266,0.00004201933,0.0004028878,0.003455508],"genre_scores_gemma":[0.9909735,0.0006264147,0.0028417,0.0007423915,0.0009609342,0.00001772662,0.0002505891,0.0001579814,0.003428716],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.9404441,"threshold_uncertainty_score":0.9996454,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02346698499936684,"score_gpt":0.2720902197349988,"score_spread":0.2486232347356319,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}