{"id":"W2091032823","doi":"10.1139/v03-113","title":"The mechanism of protonolysis of phenylplatinum(II) bonds in complexes with phenyl trans to nitrogen or carbon donors","year":2003,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Protonolysis; Benzene; Medicinal chemistry; Platinum; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001517199,0.0002814383,0.0001781245,0.0001081522,0.000161171,0.0002300031,0.0006109835,0.0005876124,0.001785668],"category_scores_gemma":[0.0002056038,0.0002316495,0.0001788398,0.00005934562,0.0004051122,0.0005013713,0.0003209173,0.0003857754,0.0005032058],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005196379,"about_ca_system_score_gemma":0.0001324523,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003878104,"about_ca_topic_score_gemma":0.0003040785,"domain_scores_codex":[0.9998983,0.0000163529,0.000006118678,0.0000230375,0.00002585265,0.00003033187],"domain_scores_gemma":[0.9999409,0.00001559846,0.00002068138,0.000006781799,0.000005682581,0.00001044193],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002332977,0.00001276272,0.0002083907,0.0001310494,0.00001280179,0.0003049617,0.00008488185,0.000361203,0.9953666,0.0007048741,0.0001291741,0.002450092],"study_design_scores_gemma":[0.00002308076,0.0001088953,0.0004853773,0.000005581822,0.00000692611,0.0002632997,0.0000217668,0.0008656466,0.9971257,0.000116497,0.0009724775,0.000004760736],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9869087,0.001636401,0.006540253,0.0003978955,0.00005056225,0.00008390398,0.0002147549,0.0001406621,0.004026713],"genre_scores_gemma":[0.9969587,0.0004326809,0.0008235999,0.00004873327,0.000006353971,0.00003298464,0.0000720967,0.000008430997,0.001616453],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001785668,"threshold_uncertainty_score":0.005973637,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009708443264630473,"score_gpt":0.1944280517104038,"score_spread":0.1847196084457733,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}