{"id":"W2091174233","doi":"10.2118/05-03-05","title":"Low-Temperature Oxidation of Oils in Terms of SARA Fractions: Why Simple Reaction Models Don't Work","year":2005,"lang":"en","type":"article","venue":"Journal of Canadian Petroleum Technology","topic":"Petroleum Processing and Analysis","field":"Chemistry","cited_by":130,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saskatchewan Research Council (Canada)","funders":"Canadian Natural Resources Limited","keywords":"Arrhenius equation; Combustion; Limiting; Fraction (chemistry); Work (physics); Reaction rate; Chemistry; Kinetics; Oxygen; Thermodynamics; Redox; Order of reaction; Chemical kinetics; Oil field; Spontaneous combustion; Chemical engineering; Organic chemistry; Reaction rate constant; Catalysis; Petroleum engineering; Activation energy; Geology; Mechanical engineering","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.002246283,0.0008276437,0.001086058,0.0005563768,0.0002820779,0.001506841,0.001565423,0.001432184,0.001159936],"category_scores_gemma":[0.004124633,0.0004958962,0.001178132,0.0004818045,0.001045157,0.003166968,0.000653971,0.001649744,0.001344768],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008527852,"about_ca_system_score_gemma":0.0006548804,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004805683,"about_ca_topic_score_gemma":0.00355624,"domain_scores_codex":[0.99945,0.0002368812,0.00003722709,0.00008221007,0.0001545493,0.00003919729],"domain_scores_gemma":[0.998648,0.0007908627,0.0001238332,0.0001488641,0.0002272492,0.00006122253],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004466395,0.0003786378,0.008959328,0.002399998,0.0004853785,0.0003033094,0.0005737836,0.7736546,0.02549048,0.08690588,0.009508639,0.0908933],"study_design_scores_gemma":[0.00005895341,0.0001779538,0.001356769,0.0002100707,0.00007114436,0.00007431352,0.0001466671,0.8783323,0.004805724,0.1049461,0.009737246,0.00008277933],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.3465032,0.04988034,0.5531737,0.02768293,0.002010799,0.0002450886,0.0008466333,0.00276007,0.01689707],"genre_scores_gemma":[0.9047698,0.02220271,0.06019928,0.001145069,0.0004777863,0.0002741159,0.0003415819,0.0006321991,0.009957398],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.004805683,"threshold_uncertainty_score":0.01187968,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007511578915777942,"score_gpt":0.2207073793610777,"score_spread":0.2131958004452997,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}