{"id":"W2091415706","doi":"10.1016/j.jms.2005.08.003","title":"Born-Oppenheimer breakdown effects and hyperfine structure in the rotational spectra of SbF and SbCl","year":2005,"lang":"en","type":"article","venue":"Journal of Molecular Spectroscopy","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; State Key Laboratory of Automotive Simulation and Control","keywords":"Hyperfine structure; Spectral line; Atomic physics; Excited state; Quadrupole; Molecule; Unpaired electron; Isotopomers; Physics; Materials science; Molecular physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002446621,0.0002779602,0.000462731,0.0001525904,0.00006746074,0.00006705913,0.0003186762,0.000163324,0.000254387],"category_scores_gemma":[0.00009118288,0.0001994424,0.000131165,0.0001900556,0.0001507373,0.0001419604,0.00004392929,0.0007404588,7.052993e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005531799,"about_ca_system_score_gemma":0.00008928833,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001278774,"about_ca_topic_score_gemma":0.00002540702,"domain_scores_codex":[0.998239,0.00008852692,0.0005503261,0.0002454144,0.0005705408,0.0003061264],"domain_scores_gemma":[0.9990182,0.0001086809,0.0004098394,0.0002768275,0.00007421233,0.0001122677],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001732346,0.00006564655,0.002487785,0.0001046971,0.0001085298,0.0002245457,0.0003899086,0.00008906842,0.9923729,0.003011641,0.0001367815,0.0008352543],"study_design_scores_gemma":[0.001718106,0.0002474437,0.01372125,0.0001198663,0.0001325853,0.00144325,0.00008874208,0.0001193227,0.9767337,0.004700809,0.0007737826,0.0002010783],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9886156,0.007598116,0.0004693118,0.001400602,0.00006147803,0.0001120093,0.00001555964,0.000006179484,0.001721186],"genre_scores_gemma":[0.9861057,0.0003111666,0.01289355,0.0003788631,0.0002585584,0.00000202327,0.000005095037,0.00002658259,0.00001847775],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01563914,"threshold_uncertainty_score":0.8133025,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.002436202417432583,"score_gpt":0.2284726435464738,"score_spread":0.2260364411290412,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}