{"id":"W2091435228","doi":"10.1002/aic.690481118","title":"Effects of diffusion‐controlled reactions on atom‐transfer radical polymerization","year":2002,"lang":"en","type":"article","venue":"AIChE Journal","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":100,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Atom-transfer radical-polymerization; Chemistry; Diffusion; Photochemistry; Methyl methacrylate; Methyl acrylate; Radical polymerization; Polymerization; Styrene; Chain transfer; Catalysis; Living free-radical polymerization; Chain termination; Polymer chemistry; Chemical physics; Monomer; Polymer; Organic chemistry; Thermodynamics; Copolymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005544318,0.001024496,0.0009778333,0.000483876,0.0005843045,0.0009558849,0.001074517,0.001314243,0.002613405],"category_scores_gemma":[0.001522507,0.0005576321,0.001145456,0.0002278475,0.001074272,0.002302633,0.0007024046,0.001027812,0.0003522555],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001400999,"about_ca_system_score_gemma":0.001036785,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004898574,"about_ca_topic_score_gemma":0.001340406,"domain_scores_codex":[0.9997544,0.00006224919,0.00001215143,0.00004958364,0.0000762725,0.00004538631],"domain_scores_gemma":[0.9995047,0.0002755032,0.00007290603,0.00004266859,0.00006612833,0.0000381306],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001150388,0.00009732717,0.0003201079,0.00009053548,0.00002474409,0.0002163909,0.00004992236,0.9374246,0.0330932,0.02573999,0.0002013608,0.00262673],"study_design_scores_gemma":[0.00003928008,0.00003812351,0.00006245298,0.000004070135,0.0000113778,0.00002129962,0.000004507619,0.9905922,0.007035955,0.001654196,0.0005246079,0.00001199446],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5969485,0.001435684,0.368907,0.00135331,0.0003078269,0.000284771,0.0002709688,0.0005011483,0.02999077],"genre_scores_gemma":[0.9825765,0.0008273834,0.009376673,0.00007761803,0.00002382652,0.0001778907,0.0000706351,0.00006355435,0.006805884],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004898574,"threshold_uncertainty_score":0.01016498,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006823242057938742,"score_gpt":0.2084791062723517,"score_spread":0.201655864214413,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}