{"id":"W2091522705","doi":"10.1021/om900127u","title":"Unsymmetrically Bridged Methyl Groups as Intermediates in the Transformation of Bridging Methylene to Bridging Acetyl Groups: Ligand Migrations and Migratory Insertions in Mixed Iridium/Ruthenium Complexes","year":2009,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Agostic interaction; Protonation; Methylene; Ruthenium; Iridium; Trifluoromethanesulfonate; Methyl group; Ligand (biochemistry); Crystallography; Migratory insertion; Stereochemistry; Deprotonation; Medicinal chemistry; Group (periodic table); Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.001048846,0.0004141703,0.0007798235,0.001055384,0.0001801585,0.0001681732,0.0006389702,0.0001572046,0.0003149031],"category_scores_gemma":[0.0005338856,0.0003623338,0.0002323097,0.002890151,0.0001372722,0.0004397744,0.00008975293,0.000402432,0.00001814667],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001519792,"about_ca_system_score_gemma":0.00007877533,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003919902,"about_ca_topic_score_gemma":0.001586637,"domain_scores_codex":[0.9970974,0.0001751876,0.001156465,0.0005423177,0.0005237386,0.0005048983],"domain_scores_gemma":[0.9983273,0.0005270229,0.0002666266,0.000599491,0.0001080788,0.0001714372],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005117397,0.0005185222,0.002036378,0.0001047899,0.000094373,0.000007089427,0.01072567,0.00005137107,0.9599668,0.001436452,0.00003003773,0.02497729],"study_design_scores_gemma":[0.00141564,0.0002007726,0.2088376,0.0002021555,0.0003084029,0.00004201941,0.006589255,0.001002608,0.7776191,0.001283189,0.00168318,0.0008160516],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.992877,0.001065763,0.001339535,0.003367794,0.00004511638,0.0003205925,0.00007118463,0.00006233119,0.0008506521],"genre_scores_gemma":[0.9982995,0.0003613728,0.0005450151,0.00042485,0.00009090814,0.00005090597,0.0001205742,0.00003921892,0.00006762031],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2068012,"threshold_uncertainty_score":0.9998829,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01420630066708135,"score_gpt":0.2436213880428936,"score_spread":0.2294150873758122,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}