{"id":"W2091522705","doi":"10.1021/om900127u","title":"Unsymmetrically Bridged Methyl Groups as Intermediates in the Transformation of Bridging Methylene to Bridging Acetyl Groups: Ligand Migrations and Migratory Insertions in Mixed Iridium/Ruthenium Complexes","year":2009,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Agostic interaction; Protonation; Methylene; Ruthenium; Iridium; Trifluoromethanesulfonate; Methyl group; Ligand (biochemistry); Crystallography; Migratory insertion; Stereochemistry; Deprotonation; Medicinal chemistry; Group (periodic table); Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002476599,0.0004287535,0.0003323954,0.0001382239,0.0001519238,0.0003037268,0.0007372723,0.0004109132,0.000981602],"category_scores_gemma":[0.0002907862,0.0002633864,0.0002019801,0.0001533163,0.0002943666,0.0003635374,0.0003930263,0.000648085,0.0002993648],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003268288,"about_ca_system_score_gemma":0.0001517973,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004421065,"about_ca_topic_score_gemma":0.0008786801,"domain_scores_codex":[0.9998388,0.00002934484,0.00001047627,0.00003185774,0.000036325,0.00005311602],"domain_scores_gemma":[0.9998989,0.00001831027,0.00003310638,0.00001880704,0.00001019528,0.00002060466],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002272033,0.00004046955,0.00008753879,0.00009897729,0.00001397854,0.0001282049,0.0001536226,0.000421329,0.9961975,0.0005399145,0.0000673841,0.002023944],"study_design_scores_gemma":[0.00004324237,0.0003906645,0.0003470521,0.000007543887,0.00001055219,0.00009767056,0.00002909112,0.0008496069,0.9970349,0.00005478341,0.001120992,0.00001393418],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957831,0.0003768162,0.001585055,0.00004971482,0.00001136863,0.00002991234,0.00007024017,0.00009646241,0.001997404],"genre_scores_gemma":[0.9970913,0.0002234291,0.001554476,0.00002365568,0.000004629082,0.00002169442,0.00006131802,0.00002939934,0.0009899886],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000981602,"threshold_uncertainty_score":0.003283799,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01420630066708135,"score_gpt":0.2436213880428936,"score_spread":0.2294150873758122,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}