{"id":"W2091609607","doi":"10.1021/om000316f","title":"Synthesis and Structure of a Hypercoordinate Silicon-Bridged [1]Ferrocenophane","year":2000,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Tetracoordinate; Chemistry; Silicon; Crystallography; Trigonal bipyramidal molecular geometry; Atom (system on chip); Trigonal crystal system; Group (periodic table); Crystal structure; Stereochemistry; Planar; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00009219434,0.0003282484,0.0006607226,0.0001238835,0.0001140614,0.00004997715,0.0003729311,0.0001624204,0.2044814],"category_scores_gemma":[0.0001374658,0.000304381,0.0001643111,0.0004531785,0.0001952163,0.0001430038,0.00008769134,0.0001659047,0.00006918852],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004006677,"about_ca_system_score_gemma":0.0000416414,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005291626,"about_ca_topic_score_gemma":0.000016023,"domain_scores_codex":[0.998356,0.00002611106,0.0004684262,0.0004964087,0.0002949273,0.0003580564],"domain_scores_gemma":[0.9987814,0.0001820892,0.0001402816,0.0006524685,0.0000605592,0.0001831415],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003318901,0.0001092993,0.0008086064,0.0001855278,0.000221111,0.000005689803,0.0001607216,0.00000565735,0.8300571,0.0001866828,0.00001788533,0.1682085],"study_design_scores_gemma":[0.0003995746,0.00002505596,0.005982249,0.00004757302,0.0004169609,0.00006286448,0.0001848767,0.0001204169,0.9626188,0.0004084999,0.02920734,0.0005258387],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9838113,0.001027085,0.000004649959,0.0001455417,0.00002070733,0.00005631572,0.0002150247,0.0000782512,0.01464109],"genre_scores_gemma":[0.9929077,0.0004781317,0.0002621802,0.00004157866,0.00008577279,0.000006637682,0.00003207821,0.00006473136,0.006121191],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2044122,"threshold_uncertainty_score":0.9999408,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00757044944022842,"score_gpt":0.1967003859553326,"score_spread":0.1891299365151042,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}