{"id":"W2091803464","doi":"10.1002/ejoc.200600922","title":"Total Synthesis of (±)‐Decursivine","year":2006,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":53,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Aldol reaction; Natural product; Adduct; Total synthesis; Substrate (aquarium); Organic chemistry; Indole test; Boron; Borylation; Aldol condensation; Combinatorial chemistry; Stereochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001259646,0.0005988859,0.0004657635,0.0003032722,0.0002927688,0.0003526885,0.0004038196,0.0002395167,0.005114278],"category_scores_gemma":[0.0001444283,0.0001799417,0.0002320353,0.0002680907,0.0001477649,0.0002539566,0.0004207968,0.0004636677,0.002395791],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003468584,"about_ca_system_score_gemma":0.000457382,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004474188,"about_ca_topic_score_gemma":0.00062279,"domain_scores_codex":[0.9998459,0.00001703788,0.00001671095,0.00003307546,0.0000395709,0.00004778586],"domain_scores_gemma":[0.9999275,0.000005740377,0.00001142713,0.00001236419,0.00001675003,0.0000260599],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002430755,0.0001039655,0.0001333394,0.000498077,0.00006165818,0.0005159249,0.0001271962,0.001295538,0.9458825,0.003446891,0.001458529,0.04623326],"study_design_scores_gemma":[0.00004421927,0.0005155909,0.0004711508,0.00003213252,0.000037939,0.0003752285,0.00001990735,0.000448477,0.9409457,0.0005929798,0.05649402,0.00002268511],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7740512,0.01095657,0.06126991,0.000541163,0.0008937965,0.0008128848,0.007685645,0.001631438,0.1421574],"genre_scores_gemma":[0.9494531,0.005163164,0.01715875,0.0001512419,0.0000665835,0.0001865492,0.002259166,0.0002321166,0.02532932],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005114278,"threshold_uncertainty_score":0.01710898,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005702307195284737,"score_gpt":0.1903644263167041,"score_spread":0.1846621191214194,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}