{"id":"W2091885653","doi":"10.1039/c2cc16751d","title":"‘Hemilabile’ silyl pincer ligation: platinum group PSiN complexes and triple C–H activation to form a (PSiC)Ru carbene complex","year":2011,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":46,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; Dalhousie University","funders":"","keywords":"Pincer movement; Silylation; Carbene; Chemistry; Platinum; Ligand (biochemistry); Pincer ligand; Medicinal chemistry; Coordination sphere; Ligation; Stereochemistry; Platinum group; Metal; Catalysis; Organic chemistry; Receptor; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001503957,0.000273504,0.0003951654,0.00009059338,0.0003658544,0.00007255771,0.001060959,0.0001434879,0.005061771],"category_scores_gemma":[0.000186207,0.000281574,0.0001317721,0.0004381452,0.0002843721,0.0002042565,0.0008250032,0.0002805114,0.00005006343],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000151954,"about_ca_system_score_gemma":0.0000314456,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002490664,"about_ca_topic_score_gemma":0.00008703292,"domain_scores_codex":[0.9984567,0.00003168479,0.0005402875,0.0004194633,0.0002410479,0.0003107936],"domain_scores_gemma":[0.9971923,0.0003179626,0.0001899536,0.001930682,0.0001314917,0.0002375638],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003350956,0.0003094849,0.0006742583,0.00005119864,0.00008505674,1.732941e-7,0.001467923,2.03385e-7,0.9800028,0.004346279,0.0005195503,0.01250955],"study_design_scores_gemma":[0.0008743227,0.0000350945,0.009562876,0.0001230302,0.0001832727,0.00001301561,0.001146814,0.001024483,0.9018708,0.005700555,0.0786786,0.0007871707],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9237353,0.0002948116,0.0006052678,0.001799524,0.0000241251,0.0002868703,0.0001417391,0.0002484755,0.07286386],"genre_scores_gemma":[0.9842977,0.00005705745,0.01397987,0.0002463622,0.00007878533,0.0002013405,0.0006558914,0.00004246044,0.000440518],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07815905,"threshold_uncertainty_score":0.9999636,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.07457492475251346,"score_gpt":0.2673853906004378,"score_spread":0.1928104658479244,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}