{"id":"W2092126377","doi":"10.1002/chin.200703248","title":"Sterically Demanding Phosphinimides: Ligands for Unique Main Group and Transition Metal Chemistry","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Steric effects; Transition metal; Group (periodic table); Combinatorial chemistry; Nanotechnology; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002313546,0.0005636734,0.0002810878,0.0001512779,0.0002636233,0.0004497902,0.000651832,0.0003144526,0.006805559],"category_scores_gemma":[0.000233604,0.0002302833,0.0001533561,0.0001790821,0.0002627611,0.0007505107,0.0006804998,0.0008793268,0.002737005],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004188184,"about_ca_system_score_gemma":0.000317821,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003016436,"about_ca_topic_score_gemma":0.0006624834,"domain_scores_codex":[0.9999173,0.0000157455,0.000004804461,0.00001885059,0.00001860241,0.00002472109],"domain_scores_gemma":[0.9999384,0.00001001209,0.00001536869,0.000006633274,0.000006066832,0.00002350023],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001322175,0.000158357,0.000178527,0.001297495,0.00003225125,0.0005843018,0.0001861969,0.001818279,0.893439,0.02601908,0.01161095,0.06335331],"study_design_scores_gemma":[0.0003085158,0.0009915234,0.0004017949,0.00006268112,0.00004450615,0.001146755,0.00009666676,0.003339243,0.8589961,0.004504989,0.1300404,0.00006680036],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7252312,0.02693211,0.1088986,0.003337952,0.001298728,0.0003907868,0.002348921,0.004313217,0.1272486],"genre_scores_gemma":[0.9273849,0.01177322,0.02725618,0.0006121337,0.0002139262,0.0002106261,0.001172826,0.0003129607,0.03106325],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006805559,"threshold_uncertainty_score":0.02276689,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0113318583875046,"score_gpt":0.2257423316410595,"score_spread":0.2144104732535549,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}