{"id":"W2092222950","doi":"10.1246/bcsj.74.103","title":"Pressure and Viscosity Effects on Thermal Geometrical Isomerization of Oxacarbocyanine Cations","year":2001,"lang":"en","type":"article","venue":"Bulletin of the Chemical Society of Japan","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of the Fraser Valley","funders":"","keywords":"Chemistry; Isomerization; Viscosity; Thermal; Thermodynamics; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006851731,0.0001212197,0.0002566974,0.000006939759,0.00005869476,0.000002736557,0.0002131916,0.0001291867,0.000144742],"category_scores_gemma":[0.0001092753,0.00009372116,0.0001927763,0.0001429726,0.000244855,0.000007286922,0.00007613435,0.0001800534,4.598749e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001389861,"about_ca_system_score_gemma":0.00001167414,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005183417,"about_ca_topic_score_gemma":1.307954e-7,"domain_scores_codex":[0.9992496,0.00001187253,0.0002189832,0.0001658703,0.0002059021,0.0001477951],"domain_scores_gemma":[0.9993532,0.0002144719,0.000118346,0.0002192497,0.00005633077,0.00003843258],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006762403,0.0001843184,0.004476522,0.0005783603,0.0001647326,2.376034e-8,0.0002455184,0.00001210221,0.9925656,0.00002209057,0.001303912,0.0003792175],"study_design_scores_gemma":[0.0004845095,0.00003139274,0.003178417,0.00009784821,0.0001106917,0.000001439691,0.00005027922,0.00004910008,0.9937741,0.00003312312,0.002106966,0.00008217718],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957338,0.0004744742,0.00001454713,0.001555735,0.00001007853,0.00008198517,0.00001940806,0.00001385544,0.002096116],"genre_scores_gemma":[0.9992493,0.0001541856,0.0001061654,0.00006766216,0.00004896504,0.00001164489,0.000008298392,0.000008851443,0.0003448631],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003515564,"threshold_uncertainty_score":0.3821838,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005876992665614871,"score_gpt":0.2035117005585537,"score_spread":0.1976347078929388,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}