{"id":"W2092372931","doi":"10.1002/ejic.200390215","title":"Synthesis and Characterization of (PTU)I<sub>2</sub> (PTU = 6‐<i>n</i>‐propyl‐2‐thiouracil) and (CMBZT)I<sub>2</sub> (CMBZT = 5‐chloro‐2‐mercaptobenzothiazole) and Possible Implications for the Mechanism of Action of Anti‐Thyroid Drugs","year":2003,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":61,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Monoclinic crystal system; Crystallography; Ligand (biochemistry); Orthorhombic crystal system; Thiocyanate; Thiouracil; Bond length; Adduct; Crystal structure; Stereochemistry; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001285769,0.0002704377,0.000685732,0.0001008743,0.0001593606,0.00003663818,0.0001772925,0.00008641151,0.00002029259],"category_scores_gemma":[0.0006467703,0.0001979948,0.0001538904,0.0002029004,0.0002271765,0.0001913882,0.00007510384,0.0002717019,8.20836e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002925686,"about_ca_system_score_gemma":0.0001312449,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000237203,"about_ca_topic_score_gemma":5.57261e-7,"domain_scores_codex":[0.9979984,0.0001902721,0.001047093,0.0002654112,0.0002834729,0.0002153667],"domain_scores_gemma":[0.9973712,0.0002971662,0.001283489,0.0003633882,0.0005211006,0.0001636465],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002167631,0.0001160443,0.000598171,0.000839868,0.0001968589,0.000001829919,0.0005377803,6.700614e-7,0.9893159,0.0001268222,0.0000361043,0.00801316],"study_design_scores_gemma":[0.0008612741,0.0002502622,0.01731925,0.0004505069,0.0005110344,0.0005112169,0.0007224375,0.00002915931,0.9789531,0.0001088386,0.0001110583,0.0001718694],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.996564,0.001341686,0.0008678564,0.0005435904,0.00007421114,0.0002918097,0.00006095343,0.00001150309,0.0002443478],"genre_scores_gemma":[0.9950928,0.004301875,0.0003341742,0.00006404305,0.0001126664,0.000004739281,0.000007332489,0.0000602297,0.00002213293],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01672108,"threshold_uncertainty_score":0.8073995,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02199624001478471,"score_gpt":0.2236554759415365,"score_spread":0.2016592359267518,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}