{"id":"W2092537765","doi":"10.1021/om030003v","title":"Synthesis, Structure, and Reactivity of an Unusual Platinum Olefin Carbene Complex, [(η<sup>4</sup>-cod)Pt{C(Ph<sub>2</sub>PNSiMe<sub>3</sub>)<sub>2</sub>-κ<i>C</i>,κ<i>N</i>}]","year":2003,"lang":"en","type":"article","venue":"Organometallics","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":89,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Carbene; Denticity; Medicinal chemistry; Phosphine; Pyridine; Electrophile; Nucleophile; Ligand (biochemistry); Platinum; Metalation; Stereochemistry; Metal; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.0008442937,0.001585885,0.00205212,0.0006087945,0.0007590317,0.0004362302,0.0009060431,0.001117838,0.0002165718],"category_scores_gemma":[0.001647879,0.001778624,0.0005519907,0.001700192,0.001096954,0.001002279,0.0004594969,0.001627275,0.0001070725],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006768525,"about_ca_system_score_gemma":0.0006862626,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000153393,"about_ca_topic_score_gemma":0.0005241988,"domain_scores_codex":[0.9928105,0.00007455867,0.00180939,0.002190281,0.001433719,0.001681547],"domain_scores_gemma":[0.993402,0.001285952,0.001181151,0.002666233,0.0005325422,0.0009321273],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001572719,0.0008563995,0.001741545,0.0004615802,0.0005511933,0.00006887575,0.0006399679,0.0006315995,0.9862263,0.0004386998,0.0001901384,0.008036471],"study_design_scores_gemma":[0.001740377,0.0001123735,0.0038357,0.0001587972,0.0007936377,0.00052723,0.0006514456,0.00158527,0.986831,0.000820517,0.001220139,0.001723505],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949477,0.0003028106,0.0001028777,0.00007592162,0.0002944359,0.0005755514,0.002367673,0.0005018737,0.0008311241],"genre_scores_gemma":[0.9968796,0.000452867,0.00032477,0.000107841,0.0004373194,0.00006908536,0.001220725,0.0004725877,0.00003525342],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006312965,"threshold_uncertainty_score":0.9996889,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01384584163056487,"score_gpt":0.2314074197312871,"score_spread":0.2175615781007222,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}