{"id":"W2092537765","doi":"10.1021/om030003v","title":"Synthesis, Structure, and Reactivity of an Unusual Platinum Olefin Carbene Complex, [(η<sup>4</sup>-cod)Pt{C(Ph<sub>2</sub>PNSiMe<sub>3</sub>)<sub>2</sub>-κ<i>C</i>,κ<i>N</i>}]","year":2003,"lang":"en","type":"article","venue":"Organometallics","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":89,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Carbene; Denticity; Medicinal chemistry; Phosphine; Pyridine; Electrophile; Nucleophile; Ligand (biochemistry); Platinum; Metalation; Stereochemistry; Metal; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007244697,0.0001936706,0.0001382542,0.0001057619,0.0001606011,0.0004057612,0.0003881381,0.0004021383,0.0008422647],"category_scores_gemma":[0.000213455,0.0001837092,0.00008639429,0.0001298118,0.0002505142,0.0002743257,0.0001945943,0.0003732572,0.0001643929],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005202646,"about_ca_system_score_gemma":0.000205802,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008767971,"about_ca_topic_score_gemma":0.001397718,"domain_scores_codex":[0.9999176,0.000006101967,0.000005032522,0.00002798822,0.00002518263,0.00001816165],"domain_scores_gemma":[0.9999356,0.000007422804,0.00001679502,0.00001460484,0.000008002142,0.00001756827],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008456141,0.00002309218,0.0001817241,0.00004059948,0.000006927547,0.00006766203,0.00002643194,0.0002995182,0.9975818,0.0002619459,0.00004971962,0.001376055],"study_design_scores_gemma":[0.00001589295,0.00009159598,0.000954194,0.000001585663,0.00000792507,0.0001309938,0.00001045053,0.0005350607,0.996534,0.00003708737,0.001675557,0.000005554907],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.993768,0.0007415232,0.002009238,0.00006063806,0.00001319416,0.00002590226,0.0001195178,0.00005354215,0.003208544],"genre_scores_gemma":[0.9970669,0.0002082803,0.001137131,0.00001954971,0.000003570957,0.000008126594,0.0001422246,0.00001327143,0.001400933],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008767971,"threshold_uncertainty_score":0.003774762,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01384584163056487,"score_gpt":0.2314074197312871,"score_spread":0.2175615781007222,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}