{"id":"W2093099939","doi":"10.1021/jp8021248","title":"Effect of Side-chain Length on the Side-chain Dynamics of α-Helical Poly(<scp>l</scp>-glutamic acid) as Probed by a Fluorescence Blob Model","year":2008,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Biopolymer Synthesis and Applications","field":"Biochemistry, Genetics and Molecular Biology","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Pyrene; Chemistry; Helix (gastropod); Fluorescence; Linker; Monomer; Side chain; Molecular dynamics; Excimer; Glutamic acid; Stereochemistry; Crystallography; Amino acid; Organic chemistry; Polymer; Computational chemistry; Biochemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004374736,0.0002509315,0.0003904209,0.00001449039,0.0001163508,0.000007518252,0.0007009482,0.0001543845,0.000003461955],"category_scores_gemma":[0.0004240483,0.0001440589,0.0003320728,0.0001281454,0.0005250059,0.000005661941,0.0001205216,0.0003911638,0.000002731574],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002518102,"about_ca_system_score_gemma":0.0001157663,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000114364,"about_ca_topic_score_gemma":8.754209e-7,"domain_scores_codex":[0.9985696,0.0001509177,0.0004367247,0.000203897,0.0003877186,0.0002511503],"domain_scores_gemma":[0.9982507,0.0004609084,0.000516367,0.0005416575,0.0001196547,0.0001107489],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001446662,0.0003084033,0.00001852974,0.00004748217,0.0000991287,0.000001365511,0.0001273697,0.0001926021,0.997243,0.0001581142,0.0005673217,0.001092054],"study_design_scores_gemma":[0.0003734628,0.0005293761,0.00002239328,0.0000555396,0.00009580768,0.00006260742,0.00008877555,0.01077434,0.9875875,0.0002521877,0.00007701758,0.00008103485],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9967651,0.0006983354,0.0008841821,0.0006198679,0.0000109319,0.0001629176,0.00005768932,0.000005202729,0.0007957464],"genre_scores_gemma":[0.9991542,0.000191507,0.00005461371,0.00006733784,0.0001905364,0.00001218134,0.00001338748,0.00002707617,0.0002891682],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01058174,"threshold_uncertainty_score":0.5874551,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005983751697978073,"score_gpt":0.229281537913524,"score_spread":0.2232977862155459,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}