{"id":"W2093213881","doi":"10.1039/b606012a","title":"The reaction of TiF<sub>4</sub>with Li(OC(CF<sub>3</sub>)<sub>2</sub>Ph): direct synthetic route to the lithium–titanium heterometallic fluoride bridged complex {Li(THF)<sub>2</sub>TiF<sub>3</sub>(OC(CF<sub>3</sub>)<sub>2</sub>Ph)<sub>2</sub>}<sub>2</sub>and Ti(OC(CF<sub>3</sub>)<sub>2</sub>Ph)<sub>4</sub>alkoxide","year":2006,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Lithium fluoride; Toluene; Dimer; Lithium (medication); Titanium; Alkoxide; Crystallography; Monomer; Solvent; Medicinal chemistry; Inorganic chemistry; Stereochemistry; Organic chemistry; Catalysis; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000904555,0.000262678,0.0002133808,0.0001438047,0.0002227553,0.0001643786,0.0004745011,0.0003695653,0.002495386],"category_scores_gemma":[0.0001355848,0.0001227189,0.0002058231,0.000149693,0.000178561,0.0002831341,0.00025412,0.0002965771,0.000596249],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006136321,"about_ca_system_score_gemma":0.0004316677,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002161127,"about_ca_topic_score_gemma":0.002999052,"domain_scores_codex":[0.9999185,0.000006778388,0.000004106113,0.00001751615,0.00002119157,0.0000320224],"domain_scores_gemma":[0.9999696,0.000003962366,0.00001034476,0.000004495982,0.00000544466,0.000006099306],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001596499,0.00002145605,0.0002388261,0.0001513154,0.00001474332,0.0001863829,0.00008168279,0.0002172467,0.9925966,0.0005707312,0.0002969368,0.005464326],"study_design_scores_gemma":[0.00001182192,0.0001401483,0.0006157589,0.000004219849,0.000009910325,0.0002523979,0.00002334077,0.0002517025,0.9931185,0.00006742531,0.005496737,0.000007934849],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9765965,0.002018071,0.01029007,0.0002545512,0.00008756575,0.00009839565,0.0004171321,0.0002162549,0.01002139],"genre_scores_gemma":[0.9858101,0.0005613214,0.005637323,0.00005190604,0.0000128833,0.00004584258,0.0002939309,0.00002937682,0.007557342],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002495386,"threshold_uncertainty_score":0.008347869,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00869589848050867,"score_gpt":0.2002049415862142,"score_spread":0.1915090431057055,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}