{"id":"W2093264061","doi":"10.1021/jo800681d","title":"Substituent Effects on Aryltrifluoroborate Solvolysis in Water: Implications for Suzuki−Miyaura Coupling and the Design of Stable <sup>18</sup>F-Labeled Aryltrifluoroborates for Use in PET Imaging","year":2008,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":110,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia; TRIUMF","funders":"","keywords":"Solvolysis; Chemistry; Substituent; Reactivity (psychology); Lability; Reagent; Rubric; Medicinal chemistry; Combinatorial chemistry; Hydrolysis; Organic chemistry; Psychology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000265159,0.000362385,0.0001464358,0.00007149165,0.0001233165,0.0002355655,0.0001867964,0.0002280507,0.00155104],"category_scores_gemma":[0.0004923207,0.0001284806,0.0000901909,0.00008944865,0.000315649,0.0004561659,0.0001366256,0.0002723124,0.0002477856],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001962777,"about_ca_system_score_gemma":0.0001567992,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006452768,"about_ca_topic_score_gemma":0.0009226745,"domain_scores_codex":[0.9998957,0.0000272504,0.000007164576,0.00002203268,0.00002155174,0.00002630772],"domain_scores_gemma":[0.9998216,0.00008326706,0.00004897399,0.00000853556,0.00002360282,0.0000140756],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001290113,0.000009121979,0.0002807281,0.0000428447,0.000003812527,0.00004550416,0.00003702864,0.0001419722,0.9971949,0.00008533608,0.00002423691,0.002005532],"study_design_scores_gemma":[0.000003569971,0.0001114123,0.0006786006,0.000001858833,0.00000403312,0.00005035459,0.00001840308,0.0002518599,0.9986035,0.00002483488,0.0002479674,0.000003619463],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.992799,0.00119629,0.004077625,0.00008260977,0.000007463409,0.00002915487,0.000153212,0.00006397758,0.001590596],"genre_scores_gemma":[0.9970913,0.0007071925,0.001401672,0.00002176995,0.000003631433,0.00001424275,0.00007755481,0.00001684839,0.000665778],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00155104,"threshold_uncertainty_score":0.005188704,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02136340314626488,"score_gpt":0.2363847144852413,"score_spread":0.2150213113389764,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}