{"id":"W2093264061","doi":"10.1021/jo800681d","title":"Substituent Effects on Aryltrifluoroborate Solvolysis in Water: Implications for Suzuki−Miyaura Coupling and the Design of Stable <sup>18</sup>F-Labeled Aryltrifluoroborates for Use in PET Imaging","year":2008,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":110,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia; TRIUMF","funders":"","keywords":"Solvolysis; Chemistry; Substituent; Reactivity (psychology); Lability; Reagent; Rubric; Medicinal chemistry; Combinatorial chemistry; Hydrolysis; Organic chemistry; Psychology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001283805,0.000388522,0.0007788919,0.00007620159,0.0002538743,0.00006131956,0.000656612,0.0001434947,0.0001461854],"category_scores_gemma":[0.0008238641,0.000244245,0.0001653066,0.0003443049,0.0003083,0.0002187582,0.00009045937,0.0005660745,0.000001085971],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002522181,"about_ca_system_score_gemma":0.0002906871,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002098535,"about_ca_topic_score_gemma":0.00000330237,"domain_scores_codex":[0.9977573,0.00003671102,0.001091037,0.0003219241,0.0002570345,0.0005360185],"domain_scores_gemma":[0.9954114,0.002915696,0.0006018391,0.0005793918,0.000361813,0.0001298614],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001352068,0.0002000543,0.006633466,0.0005350023,0.0001145618,0.00001605309,0.0005868217,0.003151684,0.9870033,0.000005192113,0.0003075399,0.00009431779],"study_design_scores_gemma":[0.007363863,0.00003156631,0.0002316521,0.0002655173,0.0002062266,0.0003350233,0.0004526046,0.005831683,0.9848079,0.0001759556,0.00003155578,0.0002664248],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9956146,0.001386451,0.001273959,0.001168335,0.00002787326,0.0004512133,0.00004085953,0.00002255155,0.00001417006],"genre_scores_gemma":[0.997616,0.00114756,0.0007404141,0.00007898968,0.0001692154,0.00005140926,0.00002735091,0.00007571743,0.00009337263],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006401814,"threshold_uncertainty_score":0.996002,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02136340314626488,"score_gpt":0.2363847144852413,"score_spread":0.2150213113389764,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}