{"id":"W2093346750","doi":"10.1002/chin.200445284","title":"The α‐Effect and Its Modulation by Solvent","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Modulation (music); Solvent; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006882237,0.00009821818,0.00007233375,0.000005443843,0.0001019584,0.0000374071,0.00008922241,0.00008870698,0.0001059238],"category_scores_gemma":[0.0001243568,0.00006984244,0.00003687891,0.00003726127,0.0000218563,0.00008993577,0.00004240592,0.000121283,0.00004000971],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001277619,"about_ca_system_score_gemma":0.00001163974,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004369731,"about_ca_topic_score_gemma":7.474908e-7,"domain_scores_codex":[0.9994457,8.491894e-8,0.0001261786,0.0001132897,0.0001541108,0.0001606767],"domain_scores_gemma":[0.9996263,0.00007751913,0.00005500277,0.000144185,0.00001910998,0.00007785003],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001403907,0.000006284732,0.000005052589,0.00003439289,0.000008942133,3.855577e-7,0.00004563233,0.000001153183,0.9214549,0.0003737611,0.0009777917,0.07707768],"study_design_scores_gemma":[0.0004432346,0.00001057262,0.000004824375,0.00001635832,0.000006566821,0.000008643684,0.0000275153,0.0001098938,0.9714695,0.0006538507,0.02716582,0.00008320744],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7645988,0.000415453,0.00001793158,0.0003840374,0.00008204206,0.0001049865,0.00000893072,0.0001350192,0.2342528],"genre_scores_gemma":[0.9941239,0.00005829067,0.00000945948,0.00003265112,0.00006002201,0.00002568591,0.000031604,0.0000107129,0.005647709],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2295251,"threshold_uncertainty_score":0.2848092,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006307407618996799,"score_gpt":0.2248571781485638,"score_spread":0.218549770529567,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}