{"id":"W2093382612","doi":"10.1021/ic050532m","title":"Synthesis of <i>c</i><i>yclo</i>-2,4,6-Triarsa-1,3,5-triazanes from <i>c</i><i>yclo</i>-2,4-Diarsa-1,3-diazanes Demonstrating the General Influence of Substituent Steric Strain on the Relative Stability of Pnictazane Oligomers","year":2005,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Synthesis and Characterization of Heterocyclic Compounds","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; Dalhousie University","funders":"","keywords":"Chemistry; Disproportionation; Steric effects; Medicinal chemistry; Pyridine; Aryl; Trimer; Substituent; Chloride; Stereochemistry; Dimer; Organic chemistry; Alkyl; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006630066,0.0003531818,0.0001652869,0.0001420217,0.000142559,0.0002248531,0.0002637928,0.0002314283,0.002465668],"category_scores_gemma":[0.00009787225,0.0001454505,0.0002134581,0.0001396345,0.0001201757,0.0001684218,0.0001721252,0.0005722133,0.001170193],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002957684,"about_ca_system_score_gemma":0.0003214182,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005610994,"about_ca_topic_score_gemma":0.001310741,"domain_scores_codex":[0.9999226,0.00000782539,0.000005634004,0.00002419667,0.00001820912,0.00002148801],"domain_scores_gemma":[0.9999195,0.000007921831,0.00002114415,0.00001033326,0.00001873539,0.00002234486],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001846425,0.000006219529,0.00001910758,0.00002637248,0.000002097773,0.00001736094,0.000009452542,0.00007181312,0.9987863,0.0000946265,0.0000245499,0.0009236464],"study_design_scores_gemma":[0.000006719808,0.0001026802,0.000283404,0.000002767312,0.000005146432,0.00005225206,0.00000926606,0.0001573788,0.9969901,0.00002236167,0.002364139,0.000003775947],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9584132,0.001129129,0.02217703,0.0001291034,0.00008024943,0.0002350266,0.001669488,0.0004639073,0.01570284],"genre_scores_gemma":[0.9582537,0.001362692,0.02138575,0.0001205452,0.0000161172,0.0002069711,0.002831147,0.0001857568,0.01563733],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002465668,"threshold_uncertainty_score":0.008248448,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01259778021561626,"score_gpt":0.2176870986931354,"score_spread":0.2050893184775192,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}