{"id":"W2093382612","doi":"10.1021/ic050532m","title":"Synthesis of <i>c</i><i>yclo</i>-2,4,6-Triarsa-1,3,5-triazanes from <i>c</i><i>yclo</i>-2,4-Diarsa-1,3-diazanes Demonstrating the General Influence of Substituent Steric Strain on the Relative Stability of Pnictazane Oligomers","year":2005,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Synthesis and Characterization of Heterocyclic Compounds","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; Dalhousie University","funders":"","keywords":"Chemistry; Disproportionation; Steric effects; Medicinal chemistry; Pyridine; Aryl; Trimer; Substituent; Chloride; Stereochemistry; Dimer; Organic chemistry; Alkyl; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006783814,0.0005906049,0.0009598733,0.00004622621,0.0002110973,0.0000478733,0.001368123,0.0003561645,0.002197345],"category_scores_gemma":[0.001165313,0.0004205711,0.0004533072,0.0003923352,0.0009270498,0.0002322446,0.0002487893,0.000586824,0.000008878055],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001408474,"about_ca_system_score_gemma":0.0002394979,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001910502,"about_ca_topic_score_gemma":0.00002364414,"domain_scores_codex":[0.9957793,0.0001867992,0.001891306,0.0007050044,0.0009316541,0.0005059277],"domain_scores_gemma":[0.9927425,0.00353702,0.001718564,0.001578905,0.0002717134,0.000151295],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001692141,0.0003673918,0.0047157,0.000256534,0.0003092859,0.000002095101,0.0008413678,0.0002557334,0.9908336,0.0001388402,0.00003870183,0.00207156],"study_design_scores_gemma":[0.0005438213,0.00002554688,0.003705905,0.0003670342,0.0002038033,0.00001307403,0.0009121321,0.0001800237,0.9927473,0.0001339853,0.0007803118,0.0003870833],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9946593,0.000400107,0.00001370853,0.0009220519,0.00006486583,0.0002351773,0.0009520806,0.00006584972,0.002686862],"genre_scores_gemma":[0.9988943,0.0001952109,0.0002226795,0.0001360628,0.0003004995,0.00005799937,0.00005799357,0.00006327205,0.00007202298],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004234962,"threshold_uncertainty_score":0.9998246,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01259778021561626,"score_gpt":0.2176870986931354,"score_spread":0.2050893184775192,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}