{"id":"W2093492211","doi":"10.1002/bmc.1198","title":"RP‐HPLC determination of phenylalkanoids and monoterpenoids in <i>Rhodiola rosea</i> and identification by LC‐ESI‐TOF","year":2009,"lang":"en","type":"article","venue":"Biomedical Chromatography","topic":"Medicinal Plants and Bioactive Compounds","field":"Biochemistry, Genetics and Molecular Biology","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Ontario Genomics; University of Ottawa","funders":"U.S. Food and Drug Administration","keywords":"Chromatography; Chemistry; Detection limit; Repeatability; Electrospray ionization; Mass spectrometry; Analyte; High-performance liquid chromatography; Phosphoric acid; Electrospray; Selected ion monitoring; Gas chromatography–mass spectrometry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002515377,0.0001362774,0.0001892346,0.0001545317,0.00003835393,0.00002036982,0.0001062027,0.0001749324,0.000003994753],"category_scores_gemma":[0.00004013074,0.000116929,0.00004191234,0.0002138701,0.0002841113,0.00001018479,0.00003459766,0.00007276516,3.607259e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000005759423,"about_ca_system_score_gemma":0.00001950922,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002214091,"about_ca_topic_score_gemma":0.000003265988,"domain_scores_codex":[0.998973,0.00004965757,0.000301229,0.0003174921,0.0001906966,0.0001678926],"domain_scores_gemma":[0.9995649,0.00001769125,0.0001066475,0.0001530513,0.00003528786,0.0001224112],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.00004970162,0.0001020655,0.007798294,0.00003699979,0.000009840639,0.000002764849,0.00003256925,1.064467e-8,0.9332814,0.0000383334,0.0006705939,0.05797741],"study_design_scores_gemma":[0.002438034,0.001536255,0.5072435,0.0001281988,0.00004883628,0.00005900069,0.0001356377,0.0003901671,0.4651522,0.0009558669,0.02145153,0.0004608195],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9934402,0.002206773,0.003642723,0.0002796554,0.0000593889,0.0001438537,0.00004802358,0.000008596854,0.0001708215],"genre_scores_gemma":[0.997994,0.0009163239,0.0005167613,0.0001980875,0.00008373193,0.000006642033,0.0002500749,0.000006654967,0.00002769072],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4994452,"threshold_uncertainty_score":0.4768228,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004207224720695612,"score_gpt":0.2359427325862547,"score_spread":0.231735507865559,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}