{"id":"W2093558217","doi":"10.1039/b210358n","title":"Convergent dendron approach using a phenol triallyl building block: synthesis of a phenol dendron containing 27 allyl termini","year":2002,"lang":"en","type":"article","venue":"New Journal of Chemistry","topic":"Dendrimers and Hyperbranched Polymers","field":"Materials Science","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Université de Bordeaux; Institut Universitaire de France; Centre National de la Recherche Scientifique; Institut national de la recherche scientifique","keywords":"Dendrimer; Chemistry; Phenol; Block (permutation group theory); Hydrosilylation; Sequence (biology); Combinatorial chemistry; Dehydrohalogenation; Organic chemistry; Biochemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006941924,0.0003054565,0.0008272757,0.0000932554,0.0001052796,0.00008775866,0.0006078351,0.0001894693,0.001771419],"category_scores_gemma":[0.000280858,0.0002841238,0.0003289557,0.0001630092,0.0001362734,0.0002706279,0.00009044265,0.0002969018,0.000009452788],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001473001,"about_ca_system_score_gemma":0.0002679946,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005295343,"about_ca_topic_score_gemma":7.378816e-7,"domain_scores_codex":[0.9973425,0.00008386351,0.00110004,0.0003092278,0.000680196,0.0004841371],"domain_scores_gemma":[0.9977215,0.000180375,0.001293787,0.0003186888,0.0001386036,0.0003470618],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002287865,0.0001604076,0.0001402714,0.0001709066,0.0001156821,0.00007241468,0.0008077408,0.0003950967,0.9951381,0.000006474405,0.0005134331,0.00225068],"study_design_scores_gemma":[0.001915224,0.00007247363,0.000007851849,0.0003984759,0.0003189061,0.001088935,0.0006005818,0.0009626923,0.9936227,0.00001703235,0.0007085001,0.0002866923],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9902868,0.003041779,0.0009142008,0.00006712575,0.0005945785,0.0001064499,0.00001070598,0.00002055276,0.004957772],"genre_scores_gemma":[0.9883599,0.00008081945,0.01027594,0.00003181678,0.0007632071,0.00000200836,5.464302e-7,0.00004357884,0.0004422],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009361737,"threshold_uncertainty_score":0.9999611,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03231832431624112,"score_gpt":0.2513007223784665,"score_spread":0.2189823980622253,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}