{"id":"W2093567868","doi":"10.1021/ic902418v","title":"Mechanistic Insight on the Hydrogenation of Conjugated Alkenes with H<sub>2</sub>Catalyzed by Early Main-Group Metal Catalysts","year":2010,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"","keywords":"Chemistry; Catalysis; Conjugated system; Metal; Group (periodic table); Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002324101,0.0009385161,0.0007990318,0.0002712997,0.0005688226,0.0005591774,0.001121257,0.0007304703,0.005025576],"category_scores_gemma":[0.0002890184,0.0003202506,0.0005742046,0.0002141769,0.0005786717,0.0007796243,0.0004398555,0.0006126338,0.0003686717],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007878359,"about_ca_system_score_gemma":0.0006582537,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003463743,"about_ca_topic_score_gemma":0.003981673,"domain_scores_codex":[0.9999206,0.00001337831,0.000001920328,0.000005489794,0.00002195589,0.00003672791],"domain_scores_gemma":[0.999923,0.00003432295,0.00001045593,0.000009028462,0.00001276739,0.00001045136],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005302831,0.0003266861,0.00450218,0.0007459013,0.0002014122,0.001270957,0.0002680689,0.8457282,0.04545832,0.08679003,0.001646589,0.01253131],"study_design_scores_gemma":[0.0002132811,0.0002852901,0.002268739,0.00003745187,0.00008844746,0.0001486397,0.0002449233,0.9628226,0.01568129,0.01583698,0.002337161,0.00003520674],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9642479,0.0006837466,0.01313051,0.0003640741,0.00006534832,0.0000641818,0.0003946697,0.0001239999,0.02092542],"genre_scores_gemma":[0.9955726,0.0004374841,0.00220446,0.00008274422,0.000008934825,0.00005089815,0.0001865851,0.00002709865,0.001429183],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005025576,"threshold_uncertainty_score":0.01681221,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00420285360272212,"score_gpt":0.1795713796608312,"score_spread":0.1753685260581091,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}