{"id":"W2093575210","doi":"10.1021/om020830g","title":"Redefining the Coordination Geometry and Reactivity of Guanidinate Complexes by Covalently Linking the Guanidinate Ligands. Synthesis and Reactivity of [RN{NH(R)}CN(CH<sub>2</sub>)<sub>2</sub>NC{NH(R)}NR]M(CH<sub>2</sub>Ph)<sub>2</sub> (R = <sup>i</sup>Pr; M = Ti, Zr)","year":2003,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Reactivity (psychology); Isocyanide; Ligand (biochemistry); Coordination sphere; Stereochemistry; Medicinal chemistry; Coordination complex; Metal; Crystallography; Crystal structure; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.005255606,0.002342508,0.003584017,0.001063369,0.001911985,0.0007124433,0.001933089,0.001257984,0.0002797354],"category_scores_gemma":[0.003971281,0.002029578,0.001241711,0.003871612,0.002016711,0.001435793,0.001407328,0.002098014,0.00006916966],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006791347,"about_ca_system_score_gemma":0.0004744754,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001570988,"about_ca_topic_score_gemma":0.000151432,"domain_scores_codex":[0.9881268,0.001035949,0.003118215,0.003004912,0.002468174,0.002245944],"domain_scores_gemma":[0.9860085,0.005562689,0.003364309,0.003405594,0.0009412394,0.0007176726],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002499218,0.001151095,0.0031905,0.001033853,0.001662612,0.00002977834,0.001177516,0.00007688101,0.929547,0.001218165,0.0003449109,0.06031778],"study_design_scores_gemma":[0.001678405,0.0002172892,0.004515464,0.0006173024,0.002319602,0.0002506445,0.002004343,0.001020601,0.9812186,0.00133004,0.002755199,0.002072525],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9897711,0.004538564,0.0004194589,0.000960007,0.0002539385,0.001069695,0.001017659,0.0003593583,0.001610168],"genre_scores_gemma":[0.9898626,0.008268436,0.0001742635,0.0001746807,0.0003064391,0.0002310805,0.0003576083,0.0005330271,0.00009183917],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05824525,"threshold_uncertainty_score":0.9993874,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01346238443011344,"score_gpt":0.2095533315610653,"score_spread":0.1960909471309518,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}