{"id":"W2093782951","doi":"10.1016/j.aca.2012.05.059","title":"Non-contact detection of chemical warfare simulant triethyl phosphate using PM-IRRAS","year":2012,"lang":"en","type":"article","venue":"Analytica Chimica Acta","topic":"Pesticide Exposure and Toxicity","field":"Agricultural and Biological Sciences","cited_by":8,"is_retracted":false,"has_abstract":false,"ca_institutions":"Defence Research and Development Canada; Acadia University; University of Guelph","funders":"Defence Research and Development Canada","keywords":"Chemistry; Detection limit; Analytical Chemistry (journal); Infrared spectroscopy; Chromatography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002125195,0.0001779745,0.000316921,0.00001803566,0.00008406358,0.00002334669,0.0002153205,0.0001508491,0.0002755128],"category_scores_gemma":[0.000110808,0.00007568414,0.0001813708,0.0003365539,0.00005360589,0.0002099034,0.00007260152,0.0001701965,0.00002168962],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004175296,"about_ca_system_score_gemma":0.00001078778,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002202728,"about_ca_topic_score_gemma":0.00004278365,"domain_scores_codex":[0.9987607,0.00003458516,0.000321313,0.0002298766,0.000224901,0.0004286002],"domain_scores_gemma":[0.9992985,0.0001867318,0.0001578479,0.00009752199,0.00006314319,0.0001962988],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005847449,0.0001403112,0.0071535,0.000006420313,0.00003857645,9.553438e-7,0.00005187002,4.729206e-7,0.9905593,0.00002068295,0.00004681324,0.001922642],"study_design_scores_gemma":[0.0001968056,0.0001455428,0.0811656,0.00002433654,0.0001140548,0.00001162125,0.00006615093,0.002982002,0.914135,0.0001143776,0.0008077032,0.0002368384],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9988843,0.00002682687,0.000007420588,0.0001970554,0.0001075907,0.0001195945,0.00002110518,0.00003535887,0.0006008064],"genre_scores_gemma":[0.9993492,0.00001389581,0.00006207561,0.0001307881,0.0003921002,0.000001765752,0.0000226543,0.000001968635,0.0000255294],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07642432,"threshold_uncertainty_score":0.308631,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02554156599379208,"score_gpt":0.2470722510402842,"score_spread":0.2215306850464921,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}