{"id":"W2093987424","doi":"10.1007/s10562-009-9960-8","title":"Nature, Environment and Quantification of Titanium Species in TiSiBEA Zeolites Investigated by XRD, NMR, DR UV–Vis and XPS","year":2009,"lang":"en","type":"article","venue":"Catalysis Letters","topic":"Zeolite Catalysis and Synthesis","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":false,"ca_institutions":"Canadian Nautical Research Society","funders":"Centre National de la Recherche Scientifique","keywords":"Silanol; Zeolite; X-ray photoelectron spectroscopy; Chemistry; Octahedron; Titanium; Molecular sieve; Inorganic chemistry; Catalysis; Crystallography; Ion; Nuclear chemistry; Physical chemistry; Crystal structure; Chemical engineering; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001871482,0.0002227581,0.0004026232,0.0001573837,0.00005519758,0.00005405711,0.0001747432,0.000176106,0.0001236891],"category_scores_gemma":[0.00009082982,0.0002160065,0.00008400808,0.0002181632,0.0002596121,0.0001586905,0.00004446885,0.0002127017,0.00000855299],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006637332,"about_ca_system_score_gemma":0.000007326056,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006743176,"about_ca_topic_score_gemma":0.000007325538,"domain_scores_codex":[0.9985682,0.00003137437,0.0004395476,0.0004850617,0.0002455674,0.0002302418],"domain_scores_gemma":[0.9990811,0.0001069408,0.0001945202,0.0004920294,0.00001799668,0.0001073564],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000118523,0.00005988679,0.01899976,0.00005120802,0.00006464548,0.000004414739,0.0002529883,0.00001087546,0.9755674,0.0001159814,0.002990574,0.001870388],"study_design_scores_gemma":[0.0003053976,0.00001067247,0.04705124,0.00004830262,0.0001458223,0.000004517822,0.0002433162,0.0001713805,0.9412255,0.00006858138,0.01043307,0.0002921837],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9930565,0.00262182,0.00003959049,0.003539863,0.00001055621,0.00005748526,0.00008326582,0.00002191804,0.0005689633],"genre_scores_gemma":[0.9974403,0.0005777261,0.0002029305,0.0006792172,0.00003165727,0.000008156137,0.0005997181,0.00001610676,0.0004441544],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03434191,"threshold_uncertainty_score":0.8808488,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00860736280029532,"score_gpt":0.1978244223909646,"score_spread":0.1892170595906693,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}