{"id":"W2093987424","doi":"10.1007/s10562-009-9960-8","title":"Nature, Environment and Quantification of Titanium Species in TiSiBEA Zeolites Investigated by XRD, NMR, DR UV–Vis and XPS","year":2009,"lang":"en","type":"article","venue":"Catalysis Letters","topic":"Zeolite Catalysis and Synthesis","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":false,"ca_institutions":"Canadian Nautical Research Society","funders":"Centre National de la Recherche Scientifique","keywords":"Silanol; Zeolite; X-ray photoelectron spectroscopy; Chemistry; Octahedron; Titanium; Molecular sieve; Inorganic chemistry; Catalysis; Crystallography; Ion; Nuclear chemistry; Physical chemistry; Crystal structure; Chemical engineering; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000248735,0.0001660312,0.00016469,0.0005578918,0.0002905467,0.0004232934,0.0002473439,0.0003238685,0.001002401],"category_scores_gemma":[0.0002988128,0.0002854317,0.0002143318,0.0002825196,0.000263148,0.0002192676,0.0001197727,0.0002026742,0.0002912301],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002517872,"about_ca_system_score_gemma":0.0002171314,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002637991,"about_ca_topic_score_gemma":0.003204737,"domain_scores_codex":[0.9998356,0.00002229883,0.00001650856,0.00003374823,0.0000544894,0.00003731707],"domain_scores_gemma":[0.9998505,0.00004271389,0.00002946271,0.00001024959,0.00004803899,0.00001905375],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001585615,0.000005644193,0.0007826929,0.00001421235,0.000004823739,0.00002086909,0.00001803421,0.00006500402,0.9983053,0.0000462979,0.000008829285,0.0005695801],"study_design_scores_gemma":[0.000009037836,0.00008716292,0.009384424,0.00000319848,0.00001488795,0.0000828073,0.00006244271,0.001076057,0.9885694,0.00005304729,0.0006512773,0.00000619],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960908,0.000322798,0.002257521,0.00002172791,0.000005668605,0.000007676237,0.0003417663,0.00002353945,0.0009284736],"genre_scores_gemma":[0.996636,0.0001849999,0.001397872,0.00001195819,0.000003300594,0.000009049077,0.0004258469,0.00001197574,0.001318981],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002637991,"threshold_uncertainty_score":0.005245268,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00860736280029532,"score_gpt":0.1978244223909646,"score_spread":0.1892170595906693,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}