{"id":"W2094115815","doi":"10.1139/v02-003","title":"Substitution reactions at the Ni(III) cation in macrobicyclic complexes Reaction of metal ion complexes prepared from ligands L<sup>1</sup> (17-oxa-1,4,8,11-tetraazabicyclo[6.5.6]nonadecane) and L<sup>2</sup> (17-oxa-1,4,8,11-tetraazabicyclo[10.5.2]nonadecane) with chloride ion","year":2002,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Cyclam; Ligand (biochemistry); Ether; Nickel; Medicinal chemistry; Substitution reaction; Dissociation (chemistry); Metal; Monoclinic crystal system; Stereochemistry; Inorganic chemistry; Crystallography; Crystal structure; Physical chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001819456,0.0002901758,0.000312003,0.000134353,0.0001642479,0.0003475343,0.0003847808,0.0002803785,0.0006344268],"category_scores_gemma":[0.000253517,0.0001928914,0.0001180454,0.0001483915,0.0002067441,0.0001972687,0.0002991482,0.0003064694,0.0003888247],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005145687,"about_ca_system_score_gemma":0.0002435157,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007147245,"about_ca_topic_score_gemma":0.001783833,"domain_scores_codex":[0.9997845,0.00003743621,0.00002015457,0.00005380378,0.00004737162,0.00005674769],"domain_scores_gemma":[0.9999096,0.00001396096,0.00002240013,0.00001433591,0.00001600982,0.00002371184],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001317212,0.00001092795,0.0001534721,0.00005378436,0.000006026207,0.00005981824,0.00005418505,0.0001735278,0.9974031,0.0001475237,0.00004179827,0.001763995],"study_design_scores_gemma":[0.000007458306,0.0001090229,0.0003126849,0.00000218218,0.000004046859,0.0000687647,0.0000109626,0.0001783651,0.9984531,0.00001215891,0.000837501,0.00000359401],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9958712,0.0007475989,0.001464252,0.0000475925,0.0000135815,0.00002876803,0.00007306879,0.00007714284,0.001676822],"genre_scores_gemma":[0.996183,0.0003805001,0.002122321,0.00002608272,0.000003497472,0.00002647013,0.00008273568,0.00001934599,0.001156113],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007147245,"threshold_uncertainty_score":0.003733456,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0288078893417547,"score_gpt":0.2285397006193176,"score_spread":0.1997318112775629,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}