{"id":"W2094249181","doi":"10.1071/ch13122","title":"Characterisation of Germanium Monohalides by Solid-State NMR Spectroscopy and First Principles Quantum Chemical Calculations","year":2013,"lang":"en","type":"article","venue":"Australian Journal of Chemistry","topic":"Boron and Carbon Nanomaterials Research","field":"Materials Science","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Respiratory Research Network; National Research Council Canada; Western University","funders":"National Research Council Canada; Fonds National de la Recherche Luxembourg; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; University of Ottawa","keywords":"Nanoclusters; Germanium; Chemistry; Quantum chemistry; Spectroscopy; Solid-state nuclear magnetic resonance; Nuclear magnetic resonance spectroscopy; Chemical physics; Amorphous solid; Physical chemistry; Germanium compounds; Quantum chemical; Computational chemistry; Crystal structure; Supramolecular chemistry; Crystallography; Molecule; Organic chemistry; Nuclear magnetic resonance; Physics; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002977815,0.0001369566,0.0002971468,0.00002784574,0.00004860755,0.0001328151,0.0002260126,0.00009290365,0.001443345],"category_scores_gemma":[0.00004099758,0.0001182934,0.00006688939,0.0000606184,0.0001884392,0.000311633,0.00004855086,0.0001343135,0.00001637585],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004848766,"about_ca_system_score_gemma":0.00006866528,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005420591,"about_ca_topic_score_gemma":6.971491e-7,"domain_scores_codex":[0.998617,0.00003457239,0.0006285434,0.0001490861,0.0003096166,0.0002611846],"domain_scores_gemma":[0.9989647,0.00003906211,0.0004474972,0.000157743,0.0001937577,0.0001972153],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003407634,0.00004792428,0.001054799,0.0001192404,0.00001308729,0.000004554839,0.0001102159,0.00001197557,0.9972449,0.000006214242,0.001326944,0.00002606222],"study_design_scores_gemma":[0.0003212523,0.00003827772,0.005810946,0.00007041161,0.00001312782,0.00007600594,0.00007232504,0.00006473235,0.9929454,0.00009110189,0.0003839085,0.0001124577],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9987715,0.00005117423,0.00003310744,0.0008336457,0.00007248837,0.00008369338,0.00003486885,0.000009793033,0.0001096582],"genre_scores_gemma":[0.9991199,0.00007222454,0.0002702519,0.00001314645,0.0001112597,0.000005376294,0.000009243487,0.00001308563,0.0003854885],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004756147,"threshold_uncertainty_score":0.9994695,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.018599393465202,"score_gpt":0.2740485631699271,"score_spread":0.2554491697047251,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}