{"id":"W2094268138","doi":"10.1021/ja000432+","title":"Iminophosphide Bonding Environments from Carbene Complexes of Iminophosphines","year":2000,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":45,"is_retracted":false,"has_abstract":false,"ca_institutions":"Dalhousie University","funders":"","keywords":"Chemistry; Carbene; Polymer chemistry; Astrobiology; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009951447,0.0004891262,0.0002908405,0.0003188921,0.0007459675,0.000541781,0.0008920744,0.0003439577,0.005146967],"category_scores_gemma":[0.0002696485,0.0002251644,0.00007890354,0.0003297064,0.0003953635,0.0005665346,0.0008780897,0.0009966257,0.0002965341],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004909917,"about_ca_system_score_gemma":0.0001613001,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009769975,"about_ca_topic_score_gemma":0.001300156,"domain_scores_codex":[0.9998798,0.00001257303,0.000003224067,0.00002631463,0.00003553775,0.00004253388],"domain_scores_gemma":[0.9999077,0.00003587552,0.00001666581,0.00001275087,0.00000988352,0.00001701204],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002129987,0.0001657328,0.001989507,0.0006718357,0.00007603582,0.001370696,0.001469251,0.006722507,0.9529376,0.01489384,0.002740832,0.01483225],"study_design_scores_gemma":[0.0002380544,0.0007217284,0.005950834,0.00008653244,0.0000785728,0.0007739085,0.001318712,0.01047805,0.9621904,0.005791626,0.01228844,0.00008323965],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9867749,0.0006229104,0.00105118,0.0001244824,0.00001564149,0.000009680131,0.0001080726,0.00005745287,0.01123566],"genre_scores_gemma":[0.9982114,0.0002866002,0.0001654795,0.00003255139,0.0000052999,0.00001173021,0.0002204524,0.00001904,0.001047382],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005146967,"threshold_uncertainty_score":0.01721835,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00723006933751959,"score_gpt":0.2205238538864735,"score_spread":0.2132937845489539,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}