{"id":"W2094540668","doi":"10.1021/jp9111348","title":"Isotope Fractionation of Mercury during Its Photochemical Reduction by Low-Molecular-Weight Organic Compounds","year":2010,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Mercury impact and mitigation studies","field":"Environmental Science","cited_by":266,"is_retracted":false,"has_abstract":true,"ca_institutions":"Trent University","funders":"","keywords":"Chemistry; Mercury (programming language); Fractionation; Isotope fractionation; Isotope; Oxalic acid; Kinetic isotope effect; Mass-independent fractionation; Cysteine; Sulfur; Photochemistry; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001556568,0.00009637873,0.0001512883,0.000007340057,0.00008514976,0.000008315644,0.0001871348,0.00004581111,0.0007862533],"category_scores_gemma":[0.00008906831,0.00006782653,0.00008358993,0.0001391128,0.000171964,0.0001797612,0.00005801984,0.0003732812,0.00001968238],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005354975,"about_ca_system_score_gemma":0.0000139605,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003673592,"about_ca_topic_score_gemma":1.715279e-7,"domain_scores_codex":[0.9991739,0.00002473786,0.0002362803,0.00007709452,0.0003778879,0.0001100326],"domain_scores_gemma":[0.9993835,0.00005406213,0.0003136337,0.000119492,0.00005329939,0.00007600176],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004234913,0.0001394059,0.00004639899,0.00001531629,0.00002518575,6.243329e-7,0.0003052586,0.0000542362,0.998024,0.000003177607,0.00129326,0.00005080755],"study_design_scores_gemma":[0.000251255,0.00001986705,0.0007230428,0.00001471173,0.00003956727,0.00007663648,0.00008737923,0.0001247277,0.9980311,0.000177862,0.0003822592,0.0000716254],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976594,0.00002514111,0.00006926127,0.0004028493,0.00004553862,0.00005311452,0.000003828746,0.00000572353,0.00173514],"genre_scores_gemma":[0.9995808,0.00001503886,0.00002071495,0.00002309162,0.0001893446,0.00000160231,0.000002663937,0.000007819628,0.0001589112],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001921411,"threshold_uncertainty_score":0.8608922,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004341885208246216,"score_gpt":0.2309713209167138,"score_spread":0.2266294357084676,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}