{"id":"W2094667017","doi":"10.1021/ac0348221","title":"Organic Cation Distributions in the Residues of Levitated Droplets with Net Charge:  Validity of the Partition Theory for Droplets Produced by an Electrospray","year":2003,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"Natural Sciences and Engineering Research Council of Canada; Simon Fraser University","keywords":"Chemistry; Rhodamine 6G; Analytical Chemistry (journal); Electrospray; Mass spectrometry; Surface charge; Electrolyte; Ion; Drop (telecommunication); Partition coefficient; Chromatography; Molecule; Electrode; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002498471,0.0002416529,0.0001971653,0.0002712961,0.0001903275,0.0005562262,0.0002650336,0.0002657811,0.0005890536],"category_scores_gemma":[0.0006176202,0.0001628547,0.0001662477,0.0001247559,0.0003962429,0.0006757257,0.0002993731,0.0004000287,0.0001993],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003061348,"about_ca_system_score_gemma":0.0001616065,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005167796,"about_ca_topic_score_gemma":0.000352045,"domain_scores_codex":[0.9997752,0.0000176527,0.00001081648,0.0000780703,0.00008986239,0.00002829785],"domain_scores_gemma":[0.9997076,0.0001042721,0.00006872652,0.0000281485,0.00006786748,0.00002338855],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002894655,0.000003882206,0.0002990123,0.00001133271,0.000002678093,0.00003343671,0.00002515964,0.00006258898,0.9987254,0.00006545884,0.000005910401,0.0007363759],"study_design_scores_gemma":[0.000008603382,0.00008807024,0.003175577,0.000002566973,0.00000511292,0.0001071837,0.00004305381,0.001871816,0.9942419,0.0001356899,0.0003149768,0.000005306839],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9716618,0.0005540975,0.0256775,0.00007607068,0.00002343152,0.00007744125,0.0002422719,0.00008018384,0.00160731],"genre_scores_gemma":[0.9886846,0.0003111833,0.009877491,0.00004855384,0.00000698009,0.00004106537,0.0001752083,0.00003748266,0.0008174274],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005890536,"threshold_uncertainty_score":0.002221107,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01511857200268964,"score_gpt":0.2668909360465309,"score_spread":0.2517723640438412,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}