{"id":"W2094687776","doi":"10.1021/ic048358+","title":"Dinitrogen Partial Reduction by Formally Zero- and Divalent Vanadium Complexes Supported by the Bis-iminopyridine System","year":2005,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":69,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Vanadium; Hexane; Diamagnetism; Divalent; Crystallography; Ligand (biochemistry); Paramagnetism; Metal; Inorganic chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008844795,0.0002446089,0.0001662149,0.00009621896,0.0001122651,0.000279826,0.0005793165,0.0001492152,0.001022417],"category_scores_gemma":[0.0001364439,0.0001042509,0.00006457176,0.00009238395,0.0001308233,0.0001421906,0.0002546036,0.0003207068,0.0002690012],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003519712,"about_ca_system_score_gemma":0.0001526578,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001350785,"about_ca_topic_score_gemma":0.002352387,"domain_scores_codex":[0.999897,0.00001615169,0.000005901769,0.00002527773,0.00003047687,0.00002505109],"domain_scores_gemma":[0.9999635,0.000004532998,0.000008513698,0.000005283926,0.000008330354,0.000009862368],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000911528,0.00001074476,0.00007192745,0.00004473276,0.000004560353,0.00002587949,0.00002671095,0.000105344,0.9980617,0.0003857857,0.00004231305,0.001129107],"study_design_scores_gemma":[0.00001090787,0.0001562843,0.0004093226,0.000004021822,0.000007463525,0.00003947945,0.00002243834,0.0006415311,0.9966366,0.00005493304,0.002012008,0.000004939629],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9935415,0.0006503294,0.001928377,0.00003813407,0.00002754162,0.000008921795,0.00009098842,0.00009278423,0.003621284],"genre_scores_gemma":[0.9960593,0.0002556539,0.001282183,0.0000113049,0.00000385776,0.000004496645,0.0001763994,0.00001881309,0.002188013],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001350785,"threshold_uncertainty_score":0.003420353,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00845649584658025,"score_gpt":0.197810319322819,"score_spread":0.1893538234762388,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}