{"id":"W2094736178","doi":"10.1016/s0378-4347(01)00111-6","title":"Initial catabolic steps of isoleucine, the R-pathway and the origin of alloisoleucine","year":2001,"lang":"en","type":"review","venue":"Journal of Chromatography B Biomedical Sciences and Applications","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":false,"ca_institutions":"McGill University","funders":"","keywords":"Isoleucine; Transamination; Chemistry; Stereochemistry; Amino acid; Biochemistry; Leucine","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["sts"],"consensus_categories":[],"category_scores_codex":[0.001062649,0.0002434153,0.001083902,0.0003234214,0.0002827648,0.00004855942,0.001023483,0.0001818423,0.0001884394],"category_scores_gemma":[0.00003540386,0.0001101393,0.0004588534,0.002224242,0.004113108,0.00006134066,0.0001415733,0.0004234278,3.751066e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001165114,"about_ca_system_score_gemma":0.0002481748,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008414992,"about_ca_topic_score_gemma":0.000006567445,"domain_scores_codex":[0.9976296,0.00005984389,0.001267842,0.000252271,0.0005745746,0.0002158636],"domain_scores_gemma":[0.996963,0.0006323758,0.001756385,0.0003846683,0.0001038525,0.0001597242],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000009486428,0.0002983123,0.00007130548,0.002811257,0.0002086116,8.952717e-7,0.00006030644,1.318632e-7,0.0001709425,0.133006,0.0005362523,0.8628265],"study_design_scores_gemma":[0.0003450449,0.00008017006,0.00001773105,0.001217065,0.0004083193,0.0002550868,0.00009825637,0.00001455225,0.00006187318,0.005200556,0.9921807,0.0001206384],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.0002842944,0.9926275,0.001382911,0.0007585314,0.00002633718,0.0004309715,0.0001405747,0.00001393159,0.004334935],"genre_scores_gemma":[0.00616728,0.9924444,0.0008518763,0.00002287983,0.0003244386,0.0001420827,0.00001061648,0.00001176885,0.00002469136],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.9916444,"threshold_uncertainty_score":0.9985971,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02739306778603129,"score_gpt":0.338167527315289,"score_spread":0.3107744595292578,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}