{"id":"W2094792559","doi":"10.1139/v00-061","title":"Glycosidase-catalyzed hydrolysis of 2-deoxyglucopyranosyl pyridinium salts: effect of the 2-OH group on binding and catalysis","year":2000,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; National Institutes of Health","keywords":"Chemistry; Pyridinium; Yeast; Hydrolysis; Catalysis; Salt (chemistry); Stereochemistry; Glycoside hydrolase; Enzyme; Medicinal chemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004198744,0.000591105,0.0007994064,0.0001062193,0.0001326957,0.0003652192,0.0005332845,0.0004471144,0.001034796],"category_scores_gemma":[0.0005667118,0.0002761052,0.0002504801,0.000216343,0.0002595633,0.0002649071,0.0002214121,0.0004198159,0.0003349759],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004223319,"about_ca_system_score_gemma":0.0003118591,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001480786,"about_ca_topic_score_gemma":0.001310619,"domain_scores_codex":[0.9996487,0.00008808701,0.00004148914,0.00007420827,0.00007073543,0.00007676546],"domain_scores_gemma":[0.9997446,0.00009155876,0.00004811872,0.00002607815,0.00003480217,0.00005480185],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003430894,0.00003900178,0.0001689716,0.00008218866,0.00001472099,0.00004016094,0.00002136117,0.0003246043,0.9973999,0.0000427958,0.00002053204,0.001502599],"study_design_scores_gemma":[0.00001877261,0.0003408435,0.0004067813,0.000002156703,0.00000833814,0.00005593654,0.000005313603,0.0002703303,0.9985833,0.000006620489,0.0002965645,0.000004999948],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961612,0.001361319,0.001490186,0.00002533331,0.00001524129,0.00003463498,0.0001129744,0.00003962175,0.0007595538],"genre_scores_gemma":[0.9961122,0.0006938117,0.002223597,0.00002363835,0.000004897926,0.00002527743,0.000223128,0.0000204222,0.0006730685],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001480786,"threshold_uncertainty_score":0.003461719,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00407957629747126,"score_gpt":0.1793156526092328,"score_spread":0.1752360763117615,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}