{"id":"W2094863579","doi":"10.1021/bc700435a","title":"Hemozymes Peroxidase Activity Of Artificial Hemoproteins Constructed From the <i>Streptomyces lividans</i> Xylanase A and Iron(III)-Carboxy-Substituted Porphyrins","year":2008,"lang":"en","type":"article","venue":"Bioconjugate Chemistry","topic":"Enzyme Catalysis and Immobilization","field":"Biochemistry, Genetics and Molecular Biology","cited_by":43,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institut National de la Recherche Scientifique","funders":"","keywords":"Chemistry; Porphyrin; Guaiacol; Imidazole; Hemeprotein; Peroxidase; Heme; Stereochemistry; Myoglobin; Steric effects; Hemin; Photochemistry; Organic chemistry; Enzyme","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001934324,0.0003074988,0.0001763775,0.00008291406,0.00005621284,0.0002477641,0.0001329421,0.0001704724,0.0005323277],"category_scores_gemma":[0.0002427811,0.0001119377,0.000191097,0.00009707356,0.0001997405,0.0001477435,0.0001639016,0.0003425025,0.0002295054],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002978653,"about_ca_system_score_gemma":0.000115337,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002728738,"about_ca_topic_score_gemma":0.000191899,"domain_scores_codex":[0.99984,0.00004608204,0.00001639063,0.00004048253,0.00003514856,0.00002176436],"domain_scores_gemma":[0.9998957,0.00003188688,0.00002536376,0.00001154888,0.00001218174,0.00002333742],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004925646,0.000009235485,0.0001058665,0.00001201306,0.000003474568,0.00001798713,0.000008779561,0.00008720053,0.9989262,0.0001178388,0.000008824521,0.000653227],"study_design_scores_gemma":[0.000007217368,0.00007910148,0.0008548102,0.000001934682,0.000005733284,0.00006808843,0.000006729918,0.000905623,0.9973671,0.0000305831,0.0006712475,0.000001805915],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9904057,0.0005142404,0.007919445,0.00003649191,0.00002323109,0.00002068911,0.00009586092,0.00007846433,0.0009057772],"genre_scores_gemma":[0.9918044,0.0001905569,0.005634281,0.0000166526,0.000004802896,0.00002248447,0.0003474291,0.00003085241,0.00194843],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005323277,"threshold_uncertainty_score":0.002161145,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01073368513979364,"score_gpt":0.2097021955133529,"score_spread":0.1989685103735592,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}