{"id":"W2094863579","doi":"10.1021/bc700435a","title":"Hemozymes Peroxidase Activity Of Artificial Hemoproteins Constructed From the <i>Streptomyces lividans</i> Xylanase A and Iron(III)-Carboxy-Substituted Porphyrins","year":2008,"lang":"en","type":"article","venue":"Bioconjugate Chemistry","topic":"Enzyme Catalysis and Immobilization","field":"Biochemistry, Genetics and Molecular Biology","cited_by":43,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institut National de la Recherche Scientifique","funders":"","keywords":"Chemistry; Porphyrin; Guaiacol; Imidazole; Hemeprotein; Peroxidase; Heme; Stereochemistry; Myoglobin; Steric effects; Hemin; Photochemistry; Organic chemistry; Enzyme","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009212369,0.0002627855,0.0002741214,0.00001453732,0.0001849208,0.00002721426,0.0002250342,0.0002291524,0.00008087903],"category_scores_gemma":[0.00009101053,0.0002136038,0.0001261385,0.0001378256,0.0006716349,0.00001272303,0.0001410375,0.0001304325,0.000002510022],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000137259,"about_ca_system_score_gemma":0.000146423,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003191347,"about_ca_topic_score_gemma":0.00003719598,"domain_scores_codex":[0.9987304,0.00004376051,0.0003176436,0.0005162344,0.0001635687,0.0002283673],"domain_scores_gemma":[0.9989485,0.00002541032,0.0002329283,0.0005748666,0.0001051297,0.000113122],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000122161,0.0001296647,0.006226538,0.00004001818,0.00007673145,0.000007150528,0.00008946659,0.000005552666,0.9926785,0.000004656839,0.000275577,0.0003439305],"study_design_scores_gemma":[0.0006905664,0.0000343771,0.004707825,0.00002665525,0.00005439719,0.00004582719,0.0002168211,0.00007014699,0.9933598,0.00000722066,0.0005398245,0.0002465518],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976537,0.001265293,0.0002509511,0.00007886967,0.0000470096,0.0002429972,0.0002571682,0.00002417957,0.0001797844],"genre_scores_gemma":[0.9983892,0.0002631782,0.0002547436,0.00005046574,0.0002138132,0.00003156182,0.000612118,0.00002292618,0.0001619386],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001518713,"threshold_uncertainty_score":0.8710508,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01073368513979364,"score_gpt":0.2097021955133529,"score_spread":0.1989685103735592,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}