{"id":"W2094906201","doi":"10.1016/j.ccr.2014.04.001","title":"The bridging azido ligand as a central “player” in high-nuclearity 3d-metal cluster chemistry","year":2014,"lang":"en","type":"article","venue":"Coordination Chemistry Reviews","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":167,"is_retracted":false,"has_abstract":false,"ca_institutions":"Brock University","funders":"European Social Fund; European Commission","keywords":"Chemistry; Lacunary function; Cluster chemistry; Magnetism; Coordination complex; Magnetic relaxation; Cluster (spacecraft); Metal; Ligand (biochemistry); Ferromagnetism; Bridging (networking); Nanotechnology; Crystallography; Computational chemistry; Chemical physics; Magnetic field; Magnetization; Organic chemistry; Condensed matter physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00225535,0.0003328523,0.0004930398,0.00002593782,0.0003968236,0.0003665088,0.0007810306,0.0001639009,0.002355964],"category_scores_gemma":[0.002413387,0.0002745197,0.0001344804,0.0003478627,0.0002063564,0.0002985283,0.0002664925,0.0003394889,0.000420989],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002012016,"about_ca_system_score_gemma":0.0000758641,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000690038,"about_ca_topic_score_gemma":0.00001789571,"domain_scores_codex":[0.9971769,0.0002526827,0.0008961289,0.0006371073,0.0004413634,0.00059581],"domain_scores_gemma":[0.9981182,0.0003489243,0.0004782707,0.0007289799,0.00016133,0.0001642492],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00003291374,0.00009394212,0.0004268794,0.0005679315,0.000006130027,0.000003203416,0.0001041307,0.00008468301,0.9393796,0.0004112108,0.01354346,0.04534596],"study_design_scores_gemma":[0.001029109,0.00002143447,0.0012486,0.0002375141,0.0000290943,0.00004988377,0.00003148232,0.006874539,0.3933047,0.0009411237,0.5957174,0.0005151367],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9698429,0.002466306,0.001436139,0.004565989,0.0006446224,0.0006902457,0.00001640441,0.0001625137,0.02017489],"genre_scores_gemma":[0.9906417,0.0004201297,0.0006695441,0.0003416209,0.0005766968,0.0001410769,0.00004217367,0.00003488262,0.007132189],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5821739,"threshold_uncertainty_score":0.9999707,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01327279408993997,"score_gpt":0.2569268932404047,"score_spread":0.2436540991504648,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}